Solvent-free microwave-assisted Bingel reaction in carbon nanohorns

被引:34
|
作者
Economopoulos, Solon P. [1 ]
Pagona, Georgia [1 ]
Yudasaka, Masako [2 ,3 ]
Iijima, Sumio [2 ,3 ]
Tagmatarchis, Nikos [1 ]
机构
[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece
[2] NEC Corp Ltd, Tsukuba, Ibaraki 3058565, Japan
[3] Natl Inst Adv Ind Sci & Technol, Nanotube Res Ctr, Tokyo, Japan
关键词
PHOTOINDUCED ELECTRON-TRANSFER; SIDEWALL-FUNCTIONALIZATION; CHEMICAL-MODIFICATION; CHARGE-SEPARATION; ORGANIC-SYNTHESIS; NANOTUBES; IRRADIATION; RELEASE; FULLERENES; PORPHYRINS;
D O I
10.1039/b910947a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper we exploit the benefits of microwave-assisted functionalization of carbon nanohorns (CNHs). Using Bingel reaction conditions we have successfully incorporated malonyl moieties in CNHs. The resulting hybrid materials were characterized by diverse and complementary analytical techniques, including Raman, UV-Vis and photoluminescence spectroscopy, transmission electron microscopy, thermogravimetric analysis, while electrochemistry was employed to determine possible variations in the energy levels when photoactive units were grafted onto the skeleton of CNHs.
引用
收藏
页码:7326 / 7331
页数:6
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