Synthesis of novel ruthenium complexes containing bidentate imidazole-based ligands

被引：42
|
作者：
Elgafi, S [1 ]
Field, LD [1 ]
Messerle, BA [1 ]
Hambley, TW [1 ]
Turner, P [1 ]
机构：
[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 13期
关键词：
D O I：
10.1039/a700474e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium(II) complexes containing the bidentate imidazole-based ligands (MeN2H2C3)(2)CO L-1, (MeN2H2C3)(2)CHOH L-2 and (MeN2H2C3)(2)CH2 L-3 (where 1-MeN2H2C3 = 1-methylimidazol-2-yl), [Ru(PPh3)(2)H(CO)L-1]Cl 1, [Ru(PPh3)(2)H(CO)L-2]Cl 2 and [Ru(PPh3)(2)H(CO)L-3]Cl 3, were synthesized by the reaction of L-1-L-3 with [Ru(PPh3)(3)H(Cl)(CO)] in toluene. The complexes were characterised by NMR spectroscopy and the crystal structures of [Ru(PPh3)(2)H(CO)L-1]BF4 4 and [Ru(PPh3)(2)H(CO)L-2]OH 5 determined.
引用
收藏
页码：2341 / 2345
页数：5
相关论文
共 50 条
  • [31] Synthesis and optical characterization of novel imidazole-based azo materials
    Fukuda, N
    Kim, JY
    Fukuda, T
    Ushijima, H
    Tamada, K
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2006, 45 (1B): : 460 - 464
  • [32] Synthesis of imidazole-containing ligands and studies on metal complexes
    Yamagiwa, Y
    Koreishi, Y
    Kiyozumi, S
    Kobayashi, M
    Kamikawa, T
    Tsukino, M
    Goi, H
    Yamamoto, M
    Munakata, M
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (11) : 3317 - 3323
  • [33] Synthesis and characterization of a series of zinc complexes incorporating monodentate and bidentate imidazole ligands.
    Schnabel, RC
    Thomas, T
    Ramakrishnan, R
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1507 - U1507
  • [34] Synthesis and structural characterization of homochiral coordination polymers with imidazole-based monocarboxylate ligands
    Borrego, Elena
    Nicasio, Antonio I.
    Alvarez, Eleuterio
    Montilla, Francisco
    Manuel Cordoba, Jose
    Galindo, Agustin
    [J]. DALTON TRANSACTIONS, 2019, 48 (24) : 8731 - 8739
  • [35] SYNTHESIS OF IMIDAZOLE-BASED COMPLEXES AND INVESTIGATION OF THEIR BACTERICIDAL PROPERTIES AGAINST SRB
    Mammadov, Ayaz M.
    [J]. PROCESSES OF PETROCHEMISTRY AND OIL REFINING, 2021, 22 (04): : 537 - 545
  • [36] Preparation of hydride complexes of ruthenium with bidentate phosphite ligands
    Bravo, Jorge
    Castro, Jesus
    Garcia-Fontan, Soledad
    Rodriguez-Martinez, M. Carmen
    Albertin, Gabriele
    Antoniutti, Stefano
    Manera, Alessandro
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (24) : 5481 - 5491
  • [37] SOME RUTHENIUM(II) CHLORIDE COMPLEXES WITH BIDENTATE LIGANDS
    SALEEM, AM
    SAMHA, HA
    HODALI, HA
    SEYAM, AM
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1992, 22 (06): : 805 - 813
  • [38] Synthesis and properties of novel Y-shaped nonlinear optical polymers containing imidazole-based chromophores
    Pan, Yang
    Tang, Xiaozhen
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 108 (05) : 2802 - 2807
  • [39] Imidazole-based fluorophores: Synthesis and applications
    Al Sharif, O. F.
    Nhari, L. M.
    El-Shishtawy, R. M.
    Asiri, A. M.
    [J]. MATERIALS TODAY CHEMISTRY, 2023, 29
  • [40] RUTHENIUM COMPLEXES CONTAINING TERTIARY PHOSPHINES AND IMIDAZOLE OR 2,2'-BIPYRIDINE LIGANDS
    BATISTA, AA
    POLATO, EA
    QUEIROZ, SL
    NASCIMENTO, OR
    JAMES, BR
    RETTIG, SJ
    [J]. INORGANICA CHIMICA ACTA, 1995, 230 (1-2) : 111 - 117
12345