Synthesis of imidazole-containing ligands and studies on metal complexes

被引：19
|
作者：
Yamagiwa, Y [1 ]
Koreishi, Y [1 ]
Kiyozumi, S [1 ]
Kobayashi, M [1 ]
Kamikawa, T [1 ]
Tsukino, M [1 ]
Goi, H [1 ]
Yamamoto, M [1 ]
Munakata, M [1 ]
机构：
[1] KINKI UNIV, FAC SCI & TECHNOL, DEPT CHEM, OSAKA, OSAKA 577, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1996年 / 69卷 / 11期
关键词：
D O I：
10.1246/bcsj.69.3317
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1,5-Di(imidazol-1-yl)-3-[2-(imidazol-1-yl,7-di(imidazol-1-yl)-4-[3-(imidazol-1-yl)propyl]heptane, N,N',N ''-tris[2-(imidazol-4-yl)ethyl]benzene-1,3 and 1,3,5-tris[3-(imidazol-1-yl)propyl]benzene (TIPB) have been synthesized for a study of the formation and characteristics of zinc complexes. TIPB forms a crystalline zinc complex, not a tetrahedral complex but an octahedral complex. Other ligands form either microcrystalline complexes or polymer complexes with zinc.
引用
收藏
页码：3317 / 3323
页数：7
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