Lattice cluster theory for pedestrians: models for random copolymer blends

被引:0
|
作者
Freed, KF
Dudowicz, J
机构
[1] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
[2] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
关键词
D O I
10.1002/1521-3900(200001)149:1<11::AID-MASY11>3.0.CO;2-N
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A simplifying version of the lattice cluster theory is formulated for binary random copolymer A(x)B(1-x)/A(y)B(1-y) blends. The underlying model is based on united atom structures for the individual monomers of A and B species. Applications of the theory to saturated poly(butadiene) blends display only semiquantitative agreement with experiment. We discuss possible routes to theoretical improvements and experiments that would be helpful in testing theory.
引用
收藏
页码:11 / 16
页数:6
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