Lattice cluster theory for pedestrians: models for random copolymer blends

被引：0

作者：

Freed, KF

Dudowicz, J

机构：

[1] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA

[2] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

MACROMOLECULAR SYMPOSIA | 2000年 / 149卷

关键词：

D O I：

10.1002/1521-3900(200001)149:1<11::AID-MASY11>3.0.CO;2-N

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A simplifying version of the lattice cluster theory is formulated for binary random copolymer A(x)B(1-x)/A(y)B(1-y) blends. The underlying model is based on united atom structures for the individual monomers of A and B species. Applications of the theory to saturated poly(butadiene) blends display only semiquantitative agreement with experiment. We discuss possible routes to theoretical improvements and experiments that would be helpful in testing theory.

引用

页码：11 / 16

页数：6

共 50 条

[11] APPLICATION OF EQUATION-OF-STATE THEORY TO RANDOM COPOLYMER SYSTEMS .2. COPOLYMER BLENDS
SHIOMI, T
EGUCHI, T
ISHIMATSU, H
IMAI, K
MACROMOLECULES, 1990, 23 (23) : 4978 - 4982
[12] Fluctuation theory of connectivities for subcritical random cluster models
Campanino, Massimo
Ioffe, Dmitry
Velenik, Yvan
ANNALS OF PROBABILITY, 2008, 36 (04): : 1287 - 1321
[13] Miscibility as a function of copolymer composition in blends of a random copolymer and a homopolymer
Jianjiang Hu
Volker Abetz
Colloid and Polymer Science, 2004, 282 : 716 - 721
[14] Miscibility as a function of copolymer composition in blends of a random copolymer and a homopolymer
Hu, J
Abetz, V
COLLOID AND POLYMER SCIENCE, 2004, 282 (07) : 716 - 721
[15] Miscibility of binary blends of ethylene/norbornene copolymers: Comparison to a lattice cluster theory
Blochowiak, M.
Pakula, T.
Butt, H.-J.
Floudas, G.
POLYMER, 2007, 48 (20) : 6010 - 6017
[16] Phase diagrams for the blends of a styrene-butadiene diblock copolymer and a styrene-butadiene random copolymer: Theory
Lee, HK
Zin, WC
MACROMOLECULES, 2000, 33 (08) : 2894 - 2900
[17] A CONSIDERATION ON MISCIBILITY BEHAVIOR IN RANDOM COPOLYMER BLENDS BASED ON THE EQUATION-OF-STATE THEORY
SHIOMI, T
IMAI, K
POLYMER, 1991, 32 (01) : 73 - 78
[18] Segregation of a random copolymer from miscible blends
Pellegrini, NN
Sikka, M
Satija, SK
Winey, KI
MACROMOLECULES, 1997, 30 (21) : 6640 - 6644
[19] COMPATIBILITY AND THERMODYNAMIC INTERACTION IN RANDOM COPOLYMER BLENDS
SHIOMI, T
IMAI, K
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 38 : 233 - 242
[20] Cluster density functional theory for lattice models based on the theory of Mobius functions
Lafuente, L
Cuesta, JA
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 2005, 38 (34): : 7461 - 7482

← 1 2 3 4 5 →