Lattice cluster theory for pedestrians: models for random copolymer blends

被引:0
|
作者
Freed, KF
Dudowicz, J
机构
[1] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
[2] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
关键词
D O I
10.1002/1521-3900(200001)149:1<11::AID-MASY11>3.0.CO;2-N
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A simplifying version of the lattice cluster theory is formulated for binary random copolymer A(x)B(1-x)/A(y)B(1-y) blends. The underlying model is based on united atom structures for the individual monomers of A and B species. Applications of the theory to saturated poly(butadiene) blends display only semiquantitative agreement with experiment. We discuss possible routes to theoretical improvements and experiments that would be helpful in testing theory.
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页码:11 / 16
页数:6
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