Macromolecular Self-Assembly of Organotin(IV) Squarates and Croconates - Preparation and Crystal Structures of [SnMe2(H2O)2]C4O4, [SnMe3]2C4O4, and [SnMe3(H2O)]2C5O5

被引：3

作者：

Liebing, Phil ^{[1
]}

Husien, Asrial A. ^{[2
]}

Fischer, Axel ^{[1
]}

Nietzschmann, Eckhart ^{[3
]}

Edelmann, Frank T. ^{[1
]}

机构：

[1] Otto von Guericke Univ, Chem Inst, Univ Pl 2, D-39106 Magdeburg, Germany

[2] Jambi Univ, Chem Educ Dept, Fac Teacher Training & Educ Sci, Jambi 36361, Indonesia

[3] Hsch Anhalt, Fachbereich Angew Biowissensch & Prozesstech, Bernburger Str 55, D-06354 Kothen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2017年 / 643卷 / 08期

关键词：

Squarate; Croconate; Tin; Oxocarbon anions; Crystal structure; SUPRAMOLECULAR STRUCTURE; COORDINATION POLYMERS; VIBRATIONAL-SPECTRA; MOLECULAR-STRUCTURE; OXOCARBON DIANIONS; INFRARED SPECTRA; AROMATIC ANIONS; COMPLEXES; ANTICANCER; CO;

D O I：

10.1002/zaac.201700042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new organotin(IV) squarates and croconates [SnMe2(H2O)(2)]C4O4 (1), [SnMe3](2)C4O4 (2), and [SnMe3(H2O)](2)C5O5 (3), were prepared by salt metathesis from the appropriate sodium salts, and characterized by single-crystal X-ray diffraction and infrared spectroscopy. While 1 and 2 are coordination polymers with bridging C4O42- anions, compound 3 exists as a monomer in the solid state. In the hydrated compounds 1 and 3, the molecules are interconnected by various types of O-H<bold>O bridges between non</bold>-coordinated carbonyl oxygen atoms and water ligands, resulting in a supramolecular layer (1, 2) or network structure (3), respectively.

引用

页码：536 / 543

页数：8

共 50 条

[21] Synthesis, spectroscopic studies and crystal structure of (Et4N)(SnMe3)7(HASO4)4 • 2H2O
Diassé-Sarr, A
Barry, AH
Jouini, T
Diop, L
Mahieu, B
Mahon, MF
Molloy, KC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (12) : 2087 - 2091
[22] Dicarboxylate groups as ligands and anions in aquamagnesium complexes:: Crystal structures of [Mg (C4H2O4)(H2O)4] • H2O and [Mg(H2O)6](C4HO4)2 • 2H2O ((C4H2O4)2- = fumarate;: (C4HO4)- = hydrogenacetylenedicarboxylate)
Baier, J
Thewalt, U
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (08): : 1890 - 1894
[23] Synthesis　and　Crystal　Structure　of　Squarate　Complex　［CuLaSm（C4O4）4（H2O）16］·2H2O
Shi Jing-Min
Yan Shi-Ping
Liao Dai-Zheng
Jiang Zong-Hui
Wang Geng-Lin (Department of Chemistry
Wang Hong-Gen
Yao Xin-Kan
[J]. Chinese Journal of Structural Chemistry, 1995, (02) : 102 - 107
[24] Synthesis and crystal structure of mer-[Co(C8H4O4)(C3H4N2)3(H2O)2]H2O
Benkanoun, A.
Fadela, Balegroune
Achoura, Guehria-Laidoudi
Slimane, Dahaoui
Claude, Lecomte
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C618 - C619
[25] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
Zheng, YQ
Kong, ZP
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
[26] Exchange interactions and spin dynamics in a [CuNd2(C4O4)4(H2O)16]·2H2O crystal
V. K. Voronkova
Yu. V. Yablokov
E. Huskowska
J. Legendziewicz
[J]. Physics of the Solid State, 1997, 39 : 1838 - 1842
[27] Single crystal study of H3O(HC2O4)(H2C2O4)(H2O)
Hamadene, M.
Kherfi, H.
Guehria-Laidoudi, A.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2007, 63 : S161 - S161
[28] One-dimensional cadmium(II) coordination polymers:: Syntheses and crystal structures of [Cd(H2O)3(C5H6O4)]•2H2O, Cd(H2O)2(C6H8O4), and Cd(H2O)2(C8H12O4)
Sun, J
Zheng, YQ
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (06): : 1001 - 1006
[29] SYNTHESIS AND CHARACTERIZATION OF BINUCLEAR OXO-VANADIUM COMPLEXES OF CARBON OXOANION LIGANDS - CRYSTAL-STRUCTURES OF THE BINUCLEAR VANADIUM(IV) COMPLEX (NH4)[V2O2(OH)(C4O4)(2)(H2O)(3)]CENTER-DOT-H2O, OF THE MIXED-VALENCE VANADIUM(V)/VANADIUM(IV)-SQUARATE SPECIES [(N-C4H9)(4)N][V2O3(C4O4)(2)(H2O)(3)]CENTER-DOT-3H2O AND [(C4H9)(4)N](4)[V4O6(C4O4)(5)(H2O)(4)]CENTER-DOT-6H2O, AND OF THE BINUCLEAR VANADIUM(IV)-OXALATE SPECIES [V2O2CL2(C2O4)(CH3OH)(4)]CENTER-DOT-2PH(4)CL
KHAN, MI
CHANG, YD
CHEN, Q
SALTA, J
LEE, YS
OCONNOR, CJ
ZUBIETA, J
[J]. INORGANIC CHEMISTRY, 1994, 33 (26) : 6340 - 6350
[30] CRYSTAL STRUCTURE OF H（PyH）3 [MO2o4 （C2o4）2 （H2o）2)2'2H2o
Yang Rongsheng Yu XiufenInstitute of Structural Chemistry
[J]. Chinese Journal of Structural Chemistry, 1985, (01) : 1 - 4

← 1 2 3 4 5 →