A nanoscale Fe(II) metal-organic framework with a bipyridinedicarboxylate ligand as a high performance heterogeneous Fenton catalyst

被引：35
|
作者：
Li, Yue
Liu, Huan
Li, Wen-Juan
Zhao, Fang-Yao
Ruan, Wen-Juan [1 ,2 ]
机构：
[1] Nankai Univ, Minist Educ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
来源：
RSC ADVANCES | 2016年 / 6卷 / 08期
基金：
中国国家自然科学基金;
关键词：
ACTIVATED CARBON; WASTE-WATER; DEGRADATION; IRON; DYE; PHOTODEGRADATION; POLLUTANTS; OXIDATION; PEROXIDE; FE;
D O I：
10.1039/c5ra22779h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
With 2,2'-bipyridine-5,5'-dicarboxylate as the ligand, a nanoscale Fe(II) MOF material (Fe-bpydc) was synthesized. Fe-bpydc could activate H2O2 to degrade organic pollutants in near neutral conditions, and its activity and stability are superior to reported results. Interestingly, Fe-bpydc only consumes H2O2 in the presence of organics, leading to high H2O2 utilization efficiency.
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页码：6756 / 6760
页数：5
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