A new layered metal-organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions

被引：141
|
作者：
Zhang, Jingming [1 ]
Biradar, Ankush V. [2 ]
Pramanik, Sanhita [1 ]
Emge, Thomas J. [1 ]
Asefa, Tewodros [1 ,2 ]
Li, Jing [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
[2] Rutgers State Univ, Dept Chem & Biochem Engn, Piscataway, NJ 08854 USA
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 52期
基金：
美国国家科学基金会;
关键词：
BUTYL HYDROPEROXIDE; STYRENE; NANOPARTICLES; OXIDATION; ALKENES; OXIDE; MOF;
D O I：
10.1039/c2cc18127d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new layered MOF material [Co(Hoba)(2)center dot 2H(2)O] (1) (H(2)oba = 4,4'-oxybis(benzoic acid)) has been synthesized and used as a highly recyclable heterogeneous catalyst for olefin epoxidation reactions. Both high conversion (96%) and high selectivity of epoxide products (96%) are achieved.
引用
收藏
页码：6541 / 6543
页数：3
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