Influence of the sol-gel method on a NiO/Al2O3 catalyst for CH4/O2 to syngas reaction

被引:8
|
作者
Zhang, YH
Xiong, GX
Kou, Y
Yang, WS
Sheng, SS
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Beijing Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源
关键词
nickel-based catalyst; methane partial oxidation to syngas; sol-gel; carbon-deposition;
D O I
10.1023/A:1005660102584
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
NiO/gamma-Al2O3 catalysts were prepared by the impregnation and the sol-gel method. The sintering and loss of nickel, carbon deposition and 80 h life-test for POM reaction over the catalyst were investigated by a now-reactor and by XPS, TG, EXAFS and AAS analysis. The results indicated that the sol-gel method could enhance the ability to suppress carbon deposition and to resist nickel sintering and loss over nickel-based catalysts.
引用
收藏
页码:325 / 329
页数:5
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