sp3 Bis-Organometallic Reagents via Catalytic 1,1-Difunctionalization of Unactivated Olefins

被引：51
|
作者：
Sun, Shang-Zheng [1 ,2 ]
Talavera, Laura [1 ,2 ]
Spiess, Philipp [1 ]
Day, Craig S. [1 ,2 ]
Martin, Ruben [1 ,3 ]
机构：
[1] Barcelona Inst Sci & Technol, Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain
[2] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, C Marcel Domingo 1, Tarragona 43007, Spain
[3] Catalan Inst Res & Adv Studies ICREA, Passeig Lluis Co 23, Barcelona 08010, Spain
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2021年 / 60卷 / 21期
基金：
欧盟地平线“2020”;
关键词：
bis-organometallic; chain-walking; Ni catalysis; olefin functionalization;
D O I：
10.1002/anie.202100810
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A catalytic 1,1-difunctionalization of unactivated olefins en route to sp(3) bis-organometallic B,B(Si)-reagents is described. The protocol is characterized by exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, constituting a new platform to access sp(3) bis-organometallics.
引用
收藏
页码：11740 / 11744
页数：5
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