Polyrotaxane-like and Interpenetrating Metal-Organic Frameworks (MOFs) Constructed from Biphenyl-4,4′-Dicarboxylate and Bis(imidazole) Ligand

被引：59
|
作者：
Liu, Yang [1 ]
Qi, Yan [1 ]
Lv, Yan-Yan [1 ]
Che, Yun-Xia [1 ]
Zheng, Ji-Min [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 11期
基金：
中国国家自然科学基金;
关键词：
CAMBRIDGE STRUCTURAL DATABASE; INORGANIC 3D NETWORKS; COORDINATION POLYMERS; 3-DIMENSIONAL NETWORKS; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; HELICAL CHAINS; CO-LIGANDS; NET; ANIONS;
D O I：
10.1021/cg9006372
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The paper presents three interesting entanglement systems, including two polyrotaxane-like and one interpene-trating frameworks, namely, [Co(L-1)(bpdc)] (1), [Co(L-2)(bpdc)] (2), and [Co(L-3)1.5(bpdc)(H2O)]center dot(L-3) (3), constructed from biphenyl-4,4'-dicarboxylate and bis(imidazole) ligands (L-1 = 1,6-bis(imidazol-1-yl)-hexane, and rods that are interlaced in a parallel fashion to result in 2D -> 2D polyrotaxane-like motifs (L-2 = 1,4-bis(imidazol-1-ylmethyl)benzene and L-3 = 1,4-bis(1-imidazolyl)-benzene)). Both compounds 1 and 2 contain loops. Compound 3 represents the first example of a triply interpenetrated 5-connected 4(4) 6(6) topology network.
引用
收藏
页码：4797 / 4801
页数：5
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