Metal-organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate: synthesis, crystal structure, and surface functionality

被引：29
|
作者：
Cheplakova, Anastasia M. [1 ,2 ]
Kovalenko, Konstantin A. [1 ,2 ]
Samsonenko, Denis G. [1 ,2 ]
Lazarenko, Vladimir A. [3 ]
Khrustalev, Victor N. [4 ]
Vinogradov, Andrey S. [5 ]
Karpov, Victor M. [5 ]
Platonov, Vyacheslav E. [5 ]
Fedin, Vladimir P. [1 ,2 ]
机构：
[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Akad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, 2 Pirogova St, Novosibirsk 630090, Russia
[3] Kurchatov Inst, Natl Res Ctr, Acad Kurchatov Sq 1, Moscow 123182, Russia
[4] Peoples Friendship Univ Russia RUDN Univ, Miklukho Maklay St 6, Moscow 117198, Russia
[5] NN Vorozhtsov Novosibirsk Inst Organ Chem SB RAS, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
TETRAFLUOROTEREPHTHALIC ACID; PHOTOLUMINESCENT COMPOUNDS; COORDINATION POLYMER; ADSORPTION; CO2; SORPTION; HYDROPHOBICITY; LUMINESCENCE; SEPARATIONS; STABILITY;
D O I：
10.1039/c7dt04566b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In contrast to aromatic carboxylates, the coordination polymers based on their perfluorinated analogues are not numerous. Here we present a series of six Zn(II) coordination polymers of different dimensionalities (1D, 2D, and 3D) and porosities based on octafluorobiphenyl-4,4'-dicarboxylate (oFBPDC(2-)) and N-containing co-ligands (ur, dabco, and bpy). These complexes are characterized by single-crystal X-ray diffraction, PXRD, FT-IR, elemental analysis, and TGA. The metal-organic frameworks [Zn-2(CH3CONH2)(2)(oFBPDC)(2)] (1) and [Zn-2(oFBPDC)(2)(dabco)] (4) are shown to be porous with BET surface areas of 470 m(2) g(-1) and 441 m(2) g(-1), respectively. In addition, compound 4 shows selectivity factors of 11.3, 4.9 and more than 6 for the binary gas mixtures CO2/N-2, CO2/CH4 and benzene/cyclohexane, respectively. The measurements for pressed powders and water droplet give water contact angles of 136 degrees for 4 and 133 degrees for (H(2)bpy)[Zn-2(bpy)(oFBPDC)(3)] (5). Low water uptake indicates that both 4 and 5 belong to highly hydrophobic solids.
引用
收藏
页码：3283 / 3297
页数：15
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