Synthesis of Octafluorobiphenyl-4,4′-dicarboxylic acid and photoluminescent compounds based thereon

被引:11
|
作者
Larionov, S. V. [1 ,3 ]
Myachina, L. I. [1 ]
Sheludyakova, L. A. [1 ]
Korolkov, I. V. [1 ,3 ]
Rakhmanova, M. I. [1 ]
Plyusnin, P. E. [1 ,3 ]
Vinogradov, A. S. [2 ]
Karpov, V. M. [2 ]
Platonov, V. E. [2 ]
Fadeeva, V. P. [2 ]
机构
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
[3] Novosibirsk State Univ, Novosibirsk 630090, Russia
关键词
octafluorobiphenyl-4,4 '-dicarboxylic acid; lanthanide; complex; photoluminescence; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; LUMINESCENCE; TETRAFLUOROTEREPHTHALATE; COMPLEXES; REAGENTS; CRYSTAL; EU(III); ANIONS; EU;
D O I
10.1134/S1070363215070075
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Octafluorobiphenyl-4,4'-dicarboxylic acid (H2L) and its complexes with Tb(III) and Eu(III) [Ln(2)(H2O)(4)(L)(3)center dot 3H(2)O and Ln(2)(phen)(2)(L)(3)center dot 2H(2)O] have been prepared; their structure has been elucidated from IR spectroscopy and X-ray diffraction analysis data. Thermal properties of the compounds have been studied. The complexes of Tb(III) and Eu(III) exhibit green and red photoluminescence, respectively.
引用
收藏
页码:1617 / 1622
页数:6
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