Evidence for a distinct C-H activation mechanism for mild dehydrogenative coupling: Electrophilic Concerted Metalation-Deprotonation (eCMD)

被引：0
|
作者：
Carrow, Brad [1 ]
机构：
[1] Princeton Univ, Chem, Princeton, NJ 08544 USA
来源：
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 257卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
73
引用
收藏
页数：1
相关论文
共 50 条
  • [31] Atom-Economical Synthesis of Unsymmetrical Ketones through Photocatalyzed C-H Activation of Alkanes and Coupling with CO and Electrophilic Alkenes
    Ryu, Ilhyong
    Tani, Akihiro
    Fukuyama, Takahide
    Ravelli, Davide
    Fagnoni, Maurizio
    Albini, Angelo
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (08) : 1869 - 1872
  • [32] Theoretical Investigations on Rh(III)-Catalyzed Cross-Dehydrogenative Aryl-Aryl Coupling via C-H Bond Activation
    Zhao, Dan
    Li, Xiaoxi
    Han, Keli
    Li, Xingwei
    Wang, Yong
    JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (12): : 2989 - 2997
  • [33] Iron-Catalyzed Dehydrogenative sp3-sp2 Coupling via Direct Oxidative C-H Activation of Acetonitrile
    Su, Huimin
    Wang, Luyao
    Rao, Honghua
    Xu, Hao
    ORGANIC LETTERS, 2017, 19 (09) : 2226 - 2229
  • [34] Synthesis and reactivity of silyl ruthenium complexes: The importance of trans effects in C-H activation, Si-C bond formation, and dehydrogenative coupling of silanes
    Dioumaev, VK
    Procopio, LJ
    Carroll, PJ
    Berry, DH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (26) : 8043 - 8058
  • [35] Chelate-Assisted Oxidative Coupling Reaction of Arylamides and Unactivated Alkenes: Mechanistic Evidence for Vinyl C-H Bond Activation Promoted by an Electrophilic Ruthenium Hydride Catalyst
    Kwon, Ki-Hyeok
    Lee, Do W.
    Yi, Chae S.
    ORGANOMETALLICS, 2010, 29 (22) : 5748 - 5750
  • [36] Catalytic C-H Activation/C-C Coupling Reaction: DFT Studies on the Mechanism, Solvent Effect, and Role of Additive
    Zhang, Lei
    Fang, De-Cai
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (06): : 2405 - 2412
  • [37] Highlight: Stereoselective Cross-Dehydrogenative Coupling Reactions Based on Sp3 C-H Activation to Give Chiral Heterocyclic Compounds
    Zhang, Ming
    Zhang, Aiqin
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2012, 49 (04) : 721 - 725
  • [38] Magnesium-Mediated Benzothiazole Activation: A Room-Temperature Cascade of C-H Deprotonation, C-C Coupling, Ring-Opening, and Nucleophilic Addition Reactions
    Blair, Victoria L.
    Clegg, William
    Kennedy, Alan R.
    Livingstone, Zoe
    Russo, Luca
    Hevia, Eva
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (42) : 9857 - 9860
  • [39] The Oxidative Mechanism in Electrophilic C-H Activation: The Case of CH2F2 and CH2Cl2
    de Petris, Giulia
    Rosi, Marzio
    Ursini, Ornella
    Troiani, Anna
    CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (03) : 588 - 595
  • [40] Evidence for an Alternative to the Oxygen Rebound Mechanism in C-H Bond Activation by Non-Heme FeIVO Complexes
    Cho, Kyung-Bin
    Wu, Xiujuan
    Lee, Yong-Min
    Kwon, Yoon Hye
    Shaik, Sason
    Nam, Wonwoo
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (50) : 20222 - 20225
12345