Evidence for a distinct C-H activation mechanism for mild dehydrogenative coupling: Electrophilic Concerted Metalation-Deprotonation (eCMD)

被引：0
|
作者：
Carrow, Brad [1 ]
机构：
[1] Princeton Univ, Chem, Princeton, NJ 08544 USA
来源：
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 257卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
73
引用
收藏
页数：1
相关论文
共 50 条
  • [21] Kinetics and mechanism of methane, methanol, and dimethyl ether C-H activation with electrophilic platinum complexes
    Owen, JS
    Labinger, JA
    Bercaw, JE
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (06) : 2005 - 2016
  • [22] Catalytic asymmetric cross-dehydrogenative coupling: activation of C-H bonds by a cooperative bimetallic catalyst system
    Cao, Weidi
    Liu, Xiaohua
    Peng, Ruixue
    He, Peng
    Lin, Lili
    Feng, Xiaoming
    CHEMICAL COMMUNICATIONS, 2013, 49 (33) : 3470 - 3472
  • [23] Copper-Mediated Selective C-H Activation and Cross-Dehydrogenative C-N Coupling of 2′-Aminoacetophenones
    Ilangovan, Andivelu
    Satish, Gandhesiri
    ORGANIC LETTERS, 2013, 15 (22) : 5726 - 5729
  • [24] Ligand-Accelerated C-H Activation Reactions: Evidence for a Switch of Mechanism
    Engle, Keary M.
    Wang, Dong-Hui
    Yu, Jin-Quan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (40) : 14137 - 14151
  • [25] RhIII-Catalyzed C(sp3)-H Bond Activation by an External Base Metalation/Deprotonation Mechanism: A Theoretical Study
    Jiang, Julong
    Ramozzi, Romain
    Morokuma, Keiji
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (31) : 11158 - 11164
  • [26] Coupling N-H Deprotonation, C-H Activation, and Oxidation: Metal-Free C(sp3)-H Aminations with Unprotected Anilines
    Evoniuk, Christopher J.
    Gomes, Gabriel dos Passos
    Hill, Sean P.
    Fujita, Satoshi
    Hanson, Kenneth
    Alabugin, Igor V.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (45) : 16210 - 16221
  • [27] Thiourea-catalyzed cross-dehydrogenative coupling of sp3 C-H with nucleophiles: Mechanism and scope
    Zhang, Zhiguo
    Gu, Kai
    Bao, Zongbi
    Xing, Huabin
    Yang, Qiwei
    Ren, Qilong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [28] Selective Cross-Dehydrogenative Coupling of Various Acyclic Enamides with Heteroarenes via Rh(III)-Catalyzed C-H Activation
    Li, Xiaolan
    Luo, Haiqing
    Song, Ruixin
    Zhang, Yuting
    Gong, Xian
    Cai, Hu
    Luo, Xuzhong
    ORGANIC LETTERS, 2023, 25 (28) : 5262 - 5267
  • [29] Diastereoselective Cross-Dehydrogenative Coupling Reactions of Amides with Diarylmethanes Using DDQ through Oxidative C-H Benzylic Activation
    Kimura, Nagisa
    Nakata, Kenya
    SYNLETT, 2024, 35 (02) : 240 - 244
  • [30] CONVERSION OF EPOXIDES TO RHODIUM ENOLATES - DIRECT EVIDENCE FOR A MECHANISM INVOLVING INITIAL C-H ACTIVATION
    WU, JX
    BERGMAN, RG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) : 7628 - 7630
12345