Evidence for a distinct C-H activation mechanism for mild dehydrogenative coupling: Electrophilic Concerted Metalation-Deprotonation (eCMD)

被引：0
|
作者：
Carrow, Brad [1 ]
机构：
[1] Princeton Univ, Chem, Princeton, NJ 08544 USA
来源：
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 257卷
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
73
引用
收藏
页数：1
相关论文
共 50 条
  • [1] Oligothiophene Synthesis by a General C-H Activation Mechanism: Electrophilic Concerted Metalation-Deprotonation (eCMD)
    Wang, Long
    Carrow, Brad P.
    ACS CATALYSIS, 2019, 9 (08) : 6821 - 6836
  • [2] C-H bond activation via concerted metalation-deprotonation at a palladium(iii) center
    Bouley, Bailey. S. S.
    Tang, Fengzhi
    Bae, Dae Young
    Mirica, Liviu. M. M.
    CHEMICAL SCIENCE, 2023, 14 (14) : 3800 - 3808
  • [3] The Activating Effect of Strong Acid for Pd-Catalyzed Directed C-H Activation by Concerted Metalation-Deprotonation Mechanism
    Jiang, Heming
    Sun, Tian-Yu
    MOLECULES, 2021, 26 (13):
  • [4] Reversible Concerted Metalation-Deprotonation C-H Bond Activation by [Cp*RhCl2]2
    VanderWeide, Andrew I.
    Brennessel, William W.
    Jones, William D.
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (20): : 12960 - 12965
  • [5] Concerted vs Nonconcerted Metalation-Deprotonation in Orthogonal Direct C-H Arylation of Heterocycles with Halides: A Computational Study
    Gandon, Vincent
    Hoarau, Christophe
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (02): : 1769 - 1778
  • [6] Regioselective Oxidative Arylation of Indoles Bearing N-Alkyl Protecting Groups: Dual C-H Functionalization via a Concerted Metalation-Deprotonation Mechanism
    Potavathri, Shathaverdhan
    Pereira, Kyle C.
    Gorelsky, Serge I.
    Pike, Andrew
    LeBris, Alexis P.
    DeBoef, Brenton
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (41) : 14676 - 14681
  • [7] Origins of regioselectivity of the palladium-catalyzed (aromatic)C-H bond metalation-deprotonation
    Gorelsky, Serge I.
    COORDINATION CHEMISTRY REVIEWS, 2013, 257 (01) : 153 - 164
  • [8] High-Valent-Cobalt-Catalyzed C-H Functionalization Based on Concerted Metalation-Deprotonation and Single-Electron-Transfer Mechanisms
    Wei, Donghui
    Zhu, Xinju
    Niu, Jun-Long
    Song, Mao-Ping
    CHEMCATCHEM, 2016, 8 (07) : 1242 - 1263
  • [9] Analysis of the Palladium-Catalyzed (Aromatic)C-H Bond Metalation-Deprotonation Mechanism Spanning the Entire Spectrum of Arenes
    Gorelsky, Serge I.
    Lapointe, David
    Fagnou, Keith
    JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (01): : 658 - 668
  • [10] Direct Observation of the Microscopic Reverse of the Ubiquitous Concerted Metalation Deprotonation Step in C-H Bond Activation Catalysis
    Hammarback, L. Anders
    Aucott, Benjamin J.
    Bray, Joshua T. W.
    Clark, Ian P.
    Towrie, Michael
    Robinson, Alan
    Fairlamb, Ian J. S.
    Lynam, Jason M.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (03) : 1356 - 1364
12345