Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(μ4-O)2] (L1=2-HNC5H5N, L2=2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

被引：27
|
作者：
Alvareza, CS
Bond, AD
Cave, D
Mosquera, MEG
Harron, EA
Layfield, RA
McPartlin, M
Rawson, JM
Wood, PT
Wright, DS
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, Oviedo 33006, Spain
[3] Univ N London, Sch Chem, London N7 9DB, England
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 24期
关键词：
D O I：
10.1039/b209496g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L-1)(4)](2) (1) and [Mn-8(L-2)(12)(mu(4)-O)(2)] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.
引用
收藏
页码：2980 / 2981
页数：2
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