Catalytic enantioselective thioester aldol reactions that are compatible with protic functional groups

被引：151

作者：

Magdziak, D ^{[1
]}

Lalic, G ^{[1
]}

Lee, HM ^{[1
]}

Fortner, KC ^{[1
]}

Aloise, AD ^{[1
]}

Shair, MD ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 20期

关键词：

D O I：

10.1021/ja051759j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication reports highly enantioselective and diastereoselective methyl malonic acid half thioester (MeMAHT) aldol reactions that are compatible with protic functional groups and enolizable aldehydes, affording syn S-phenyl thiopropionates. Copyright © 2005 American Chemical Society.

引用

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页码：7284 / 7285

页数：2

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