Thermal stability and adiabatic kinetics of four explosives

被引：0

作者：

Feng, CG ^{[1
]}

Liu, L ^{[1
]}

Qian, XM ^{[1
]}

Zhu, HQ ^{[1
]}

机构：

[1] Beijing Inst Technol, State Key Lab Prevent & Control Explos Disasters, Beijing 100081, Peoples R China

来源：

THEORY AND PRACTICE OF ENERGETIC MATERIALS, VOL 5, PARTS A AND B | 2003年

关键词：

explosive; thermal decomposition; kinetics; ARC;

D O I：

暂无

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Four kinds of explosives, RDX, FMX, TATB and epsilon-CL-20, are studied by using Accelerating Rate Calorimeter (ARC). Their exothermic behaviors are described. The mechanisms of the thermal decomposition are discussed briefly and their kinetic parameters are determined in the present paper. The values of the activation energies of RDX, HMX, TATB and epsilon-CL-20 are 267.40, 368.66, 387.76 and 592.96 kJ(.)mol(-1) respectively, and their equations of compensation effect are respectively ln A = 0.2741E - 7.7087, ln A = 0.2414E - 7.1786, ln A = 0.2063E - 9.7128 and ln A = 0.2497E - 6.7068.

引用

页码：177 / 182

页数：6

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