Thermal stability of 2-etylhexyl nitrate evaluated in adiabatic calorimeter

被引:0
|
作者
Halat, Adam [1 ]
Kedzior, Renata [1 ]
Falewicz, Piotr [1 ]
Grzesiak, Dawid [1 ]
机构
[1] Wroclaw Univ Technol, PL-50370 Wroclaw, Poland
来源
PRZEMYSL CHEMICZNY | 2015年 / 94卷 / 11期
关键词
2-ETHYLHEXYL NITRATE;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2-Ethylhexyl nitrate was studied for thermal decompn. up to 350 degrees C by adiabatic calorimetry in pure form, in n-decane soln. and in a corn. product used for increasing cetane no. of gas oil to det. the reaction kinetics. The activation energy of the reaction was 190 kJ/mol and the frequency factor 3.4.10(16) s(-1). The self-accelerating decompn. temp. of corn. product in the 10(3) kg package was 75 degrees C (the recommended limit 55 degrees C).
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页码:1973 / 1976
页数:4
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