The first heterohexametallic transition-metal complex

被引：26
|
作者：
Packheiser, Rico [1 ]
Lang, Heinrich [1 ]
机构：
[1] Tech Univ Chemnitz, Fak Naturwissenschaften, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 24期
关键词：
heteromultimetallic; transition metal; acetylides; organometallic pi-tweezers; transmetallation; mass spectrometry;
D O I：
10.1002/ejic.200700617
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterisation of a first heteromultimetallic transition metal complex with six different metal atoms (Fe, Ru, Re, An, Cu and Ti), connected through carbon-rich bridging units, are reported. Complex {1-[(eta(2)-dppf)(eta(5)-C5H5)RuC C]-3-[(bipy*)(CO)(3)ReC C]-5-[PPh2AuC C-bipy({[Ti](mu-sigma,pi-C CSiMe3)(2)}Cu)]C6H3}PF6 is accessible in a consecutive reaction sequence by applying building blocks from a ligand and coordination complex library. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
引用
收藏
页码：3786 / 3788
页数：3
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