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General and efficient synthesis of meso- and β-perfluoroalkylated porphyrins via Pd-catalyzed cross-coupling reaction
被引:26
|作者:
Liu, C
[1
]
Chen, QY
[1
]
机构:
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
来源:
关键词:
brominated porphyrins;
AsPh3;
perfluoroalkylation;
Pd-2(dba)(3)center dot CHCl3;
D O I:
10.1055/s-2005-868484
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A general and efficient method has been developed for the synthesis of meso- and beta-perfluoroalkyl-substituted porphyrins via Pd-catalyzed cross-coupling reaction of meso- and beta-brominated porphyrins with perfluoroalkyl iodides and copper.
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页码:1306 / 1310
页数:5
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