General and efficient synthesis of meso- and β-perfluoroalkylated porphyrins via Pd-catalyzed cross-coupling reaction

被引:26
|
作者
Liu, C [1 ]
Chen, QY [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
关键词
brominated porphyrins; AsPh3; perfluoroalkylation; Pd-2(dba)(3)center dot CHCl3;
D O I
10.1055/s-2005-868484
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A general and efficient method has been developed for the synthesis of meso- and beta-perfluoroalkyl-substituted porphyrins via Pd-catalyzed cross-coupling reaction of meso- and beta-brominated porphyrins with perfluoroalkyl iodides and copper.
引用
收藏
页码:1306 / 1310
页数:5
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