General and efficient synthesis of meso- and β-perfluoroalkylated porphyrins via Pd-catalyzed cross-coupling reaction

被引:26
|
作者
Liu, C [1 ]
Chen, QY [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
关键词
brominated porphyrins; AsPh3; perfluoroalkylation; Pd-2(dba)(3)center dot CHCl3;
D O I
10.1055/s-2005-868484
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A general and efficient method has been developed for the synthesis of meso- and beta-perfluoroalkyl-substituted porphyrins via Pd-catalyzed cross-coupling reaction of meso- and beta-brominated porphyrins with perfluoroalkyl iodides and copper.
引用
收藏
页码:1306 / 1310
页数:5
相关论文
共 50 条
  • [21] Recent Advances in Pd-Catalyzed Cross-Coupling Reaction in Ionic Liquids
    Li, Jianxiao
    Yang, Shaorong
    Wu, Wanqing
    Jiang, Huanfeng
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (11) : 1284 - 1306
  • [22] Highly efficient Pd-catalyzed carbonylative cross-coupling reactions with tetraorganoindates
    Lee, SW
    Lee, K
    Seomoon, D
    Kim, S
    Kim, H
    Kim, H
    Shim, E
    Lee, M
    Lee, S
    Kim, M
    Lee, PH
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (14): : 4852 - 4855
  • [23] Pd-catalyzed cross-coupling reaction of styryltrifluoroborates with activated alkynes and alkanes
    Shaban, Wejdan
    Al-Masum, Mohammad
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [24] Halogenated 2′-chlorobithiazoles via Pd-catalyzed cross-coupling reactions
    Stanetty, P
    Schnürch, M
    Mihovilovic, MD
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (10): : 3754 - 3761
  • [25] An efficient synthesis of dihydroxyfluorenones via in situ Pd(0)-catalyzed cross-coupling
    Ciske, FL
    Jones, WD
    [J]. SYNTHESIS-STUTTGART, 1998, (08): : 1195 - 1198
  • [26] General and efficient route for the synthesis of 3,4-disubstituted coumarins via Pd-catalyzed site-selective cross-coupling reactions
    Zhang, Liang
    Meng, Tianhao
    Fan, Renhua
    Wu, He
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (19): : 7279 - 7286
  • [27] Sequential and iterative Pd-catalyzed cross-coupling reactions in organic synthesis
    Dobrounig, Patrick
    Trobe, Melanie
    Breinbauer, Rolf
    [J]. MONATSHEFTE FUR CHEMIE, 2017, 148 (01): : 3 - 35
  • [28] Synthesis of glucoside-based imidazolium salts for Pd-catalyzed cross-coupling reaction in water
    Zhou, Zhonggao
    Xie, Qian
    Zhou, Xin
    Yuan, Yangyang
    Pan, Yan
    Lu, Dongliang
    Du, Ziyi
    Xue, Jun
    [J]. CARBOHYDRATE RESEARCH, 2020, 496
  • [29] Sequential and iterative Pd-catalyzed cross-coupling reactions in organic synthesis
    Patrick Dobrounig
    Melanie Trobe
    Rolf Breinbauer
    [J]. Monatshefte für Chemie - Chemical Monthly, 2017, 148 : 3 - 35
  • [30] Synthesis and Functionalization of Allenes by Direct Pd-Catalyzed Organolithium Cross-Coupling
    Mateos-Gil, Jaime
    Mondal, Anirban
    Castineira Reis, Marta
    Feringa, Ben L.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (20) : 7823 - 7829