Synthesis of [3-(Trimethylsilyl)prop-2-yn-1-yl] Selenides

被引：4
|
作者：
Musalov, M. V. [1 ]
Andreev, M. V. [1 ]
Amosova, S. V. [1 ]
Larina, L. I. [1 ]
Potapov, V. A. [1 ]
机构：
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Ul Favorskogo 1, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 53卷 / 10期
关键词：
PROPARGYL SELENIDES; TELLURIDES; ANIONS;
D O I：
10.1134/S1070428017100049
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Efficient and selective methods have been developed for the synthesis of previously unknown organyl [3-(trimethylsilyl)prop-2-yn-1-yl] selenides, organyl prop-2-yn-1-yl selenides, and bis[3-(trimethyl-silyl)prop-2-yn-1-yl] selenide by reactions of 3-bromo-1-(trimethylsilyl)prop-1-yne with the corresponding organylselenolates and sodium selenide generated from diorganyl diselenides or elemental selenium by the action of sodium tetrahydridoborate.
引用
收藏
页码：1510 / 1513
页数：4
相关论文
共 50 条
  • [1] Synthesis of [3-(trimethylsilyl)prop-2-yn-1-yl] selenides
    M. V. Musalov
    M. V. Andreev
    S. V. Amosova
    L. I. Larina
    V. A. Potapov
    Russian Journal of Organic Chemistry, 2017, 53 : 1510 - 1513
  • [2] Triphenyl(prop-2-yn-1-yl)silane
    Nelson, Bjoern
    Schulte, Michaela
    Strohmann, Carsten
    Preut, Hans
    Hiersemann, Martin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O452 - U1084
  • [3] Sonogashira reaction of 5-substituted 3-(prop-2-yn-1-yl)oxolan-2-ones
    T. V. Ghochikyan
    M. A. Samvelyan
    A. S. Galstyan
    A. Gevorgyan
    G. Vardanyan
    T. Grigoryan
    P. Langer
    Russian Journal of Organic Chemistry, 2017, 53 : 1833 - 1839
  • [4] Sonogashira Reaction of 5-Substituted 3-(Prop-2-yn-1-yl) oxolan-2-ones
    Ghochikyan, T. V.
    Samvelyan, M. A.
    Galstyan, A. S.
    Gevorgyan, A.
    Vardanyan, G.
    Grigoryan, T.
    Langer, P.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 53 (12) : 1833 - 1839
  • [5] Reaction of bis(prop-2-yn-1-yl) sulfide with sulfur dichloride. First example of cyclization of bis(prop-2-yn-1-yl) chalcogenides by the action of chalcogen halides
    A. V. Martynov
    S. V. Amosova
    Russian Journal of Organic Chemistry, 2011, 47 : 1894 - 1895
  • [6] Base-Free Synthesis and Synthetic Applications of Novel 3-(Organochalcogenyl)prop-2-yn-1-yl Esters: Promising Anticancer Agents
    Gritzenco, Fabiane
    Kazmierczak, Jean C.
    Anjos, Thiago
    Speranca, Adriane
    Peixoto, Maura L. B.
    Godoi, Marcelo
    Ledebuhr, Kauane N. B.
    Bruning, Cesar Augusto
    Zamin, Lauren L.
    Godoi, Benhur
    SYNTHESIS-STUTTGART, 2021, 53 (15): : 2676 - 2688
  • [7] Reaction of Bis(prop-2-yn-1-yl) Sulfide with Sulfur Dichloride. First Example of Cyclization of Bis(prop-2-yn-1-yl) Chalcogenides by the Action of Chalcogen Halides
    Martynov, A. V.
    Amosova, S. V.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 47 (12) : 1894 - 1895
  • [8] Diastereoselective Synthesis of 3-[2-Chloro(bromo)phenyl]-2-methyl-2-[(prop-2-yn-1-yl)oxy]oxiranes and 5-[3-Chloro(bromo)phenyl]-2,2,4-trimethyl-4-[(prop-2-yn-1-yl)]-1,3-dioxolane
    Talybov, G. M.
    Akhmedova, N. Ya.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 59 (05) : 764 - 768
  • [9] Diastereoselective Synthesis of 3-[2-Chloro(bromo)phenyl]-2-methyl-2-[(prop-2-yn-1-yl)oxy]oxiranes and 5-[3-Chloro(bromo)phenyl]-2,2,4-trimethyl-4-[(prop-2-yn-1-yl)]-1,3-dioxolane
    G. M. Talybov
    N. Ya. Akhmedova
    Russian Journal of Organic Chemistry, 2023, 59 : 764 - 768
  • [10] Crystal structure of bis(prop-2-yn-1-yl)5-nitroisophthalate
    Ezhilarasi, K. S.
    Selvarani, Sivasamy
    Rajakumar, Perumal
    Revathi, B. K.
    Usha, G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O435 - U458
12345