Diastereoselective Synthesis of 3-[2-Chloro(bromo)phenyl]-2-methyl-2-[(prop-2-yn-1-yl)oxy]oxiranes and 5-[3-Chloro(bromo)phenyl]-2,2,4-trimethyl-4-[(prop-2-yn-1-yl)]-1,3-dioxolane

被引：0
|
作者：
Talybov, G. M. [1 ]
Akhmedova, N. Ya. [1 ]
机构：
[1] Azerbaijan Tech Univ, Baku 1073, Azerbaijan
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 59卷 / 05期
关键词：
halogenated benzaldehydes; 3-(1-chloroethoxy)prop-1-yne; unsaturated ethers of 2-hydroxyoxirane; substituted; 1; 3-dioxolanes;
D O I：
10.1134/S1070428023050032
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of halogen-substituted benzaldehydes with 3-(1-chloroethoxy)prop-1-yne leads to the formation of unsaturated ethers derived from 2-hydroxyoxirane. The formation of the latter was confirmed by its reaction with acetone in the presence of BF3 & BULL;Et2O to give substituted 1,3-dioxolanes.
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页码：764 / 768
页数：5
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