Diastereoselective Synthesis of 3-[2-Chloro(bromo)phenyl]-2-methyl-2-[(prop-2-yn-1-yl)oxy]oxiranes and 5-[3-Chloro(bromo)phenyl]-2,2,4-trimethyl-4-[(prop-2-yn-1-yl)]-1,3-dioxolane

被引：0

作者：

Talybov, G. M. ^{[1
]}

Akhmedova, N. Ya. ^{[1
]}

机构：

[1] Azerbaijan Tech Univ, Baku 1073, Azerbaijan

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 59卷 / 05期

关键词：

halogenated benzaldehydes; 3-(1-chloroethoxy)prop-1-yne; unsaturated ethers of 2-hydroxyoxirane; substituted; 1; 3-dioxolanes;

D O I：

10.1134/S1070428023050032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of halogen-substituted benzaldehydes with 3-(1-chloroethoxy)prop-1-yne leads to the formation of unsaturated ethers derived from 2-hydroxyoxirane. The formation of the latter was confirmed by its reaction with acetone in the presence of BF3 & BULL;Et2O to give substituted 1,3-dioxolanes.

引用

页码：764 / 768

页数：5

共 50 条

[31] The Grignard Reaction of 2-Bromo-3-(Prop-2-yn-1-yloxy) pyridine with 1-Chloro-1,1,2,2,2-pentamethyldisilane
Shin, Hong Hee
Park, Seung Ki
JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2018, 62 (04): : 314 - 318
[32] Crystal Structure, DFT Calculation, and Hirshfeld Surface Analysis of the 1-(Cyclohex-1-en-1-yl)-3-(prop-2-yn-1-yl)-1,3-dihydro-2H-benzimidazol-2-one
Adardour, Mohamed
Ait Lahcen, Marouane
Hdoufane, Ismail
Alanazi, Mohammed M.
Loughzail, Mohamed
Mousser, Henia
Fleutot, Solenne
Francois, Michel
Cherqaoui, Driss
Baouid, Abdesselam
CRYSTALS, 2023, 13 (12)
[33] Iron-Catalyzed Synthesis of Benzosultams from N-Phenyl-N-(prop-2-yn-1-yl)benzenesulfonamide and Benzenesulfonyl Hydrazine
Zhang, Mei
Yu, Xiao
Zhu, Wenjing
Liu, Yi
Zhang, Zenghui
Zhao, Jinbo
Xia, Chengcai
Li, Ke
ORGANIC LETTERS, 2023, : 603 - 607
[34] Dopaminergic receptors involvement in the antidepressant-like effect of N-(3-((3-(trifluoromethyl)phenyl)selanyl)prop-2-yn-1-yl) benzamide in mice
Pires, Camila Simoes
da Rocha, Marcia Juciele
Presa, Marcelo Heinemann
Zuge, Narryman Pinto
Besckow, Evelyn Mianes
Ledebuhr, Kauane Nayara Bahr
Kuntz, Natalia Emanuele Biolosor
Godoi, Benhur
Bortolatto, Cristiani Folharini
Bruning, Cesar Augusto
NEUROSCIENCE LETTERS, 2025, 849
[35] (2Z)-2-Benzylidene-4-(prop-2-yn-1-yl)-2H-1,4-benzothiazin-3(4H)-one
Sebbar, Nada Kheira
Zerzouf, Abdelfettah
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O614 - +
[36] Crystal structure of 1 '-(prop-2-yn-1-yl)-1,4-dihydrospiro[benzo[d][1,3]oxazine-2,3 '-indolin]-2 '-one
AaminaNaaz, Y.
Kamalraja, J.
Vimala, G.
Perumal, P. T.
SubbiahPandi, A.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O510 - U463
[37] Crystal structure and Hirshfeld surface analysis of 1-benzyl-3-(prop-2-yn-1-yl)-2,3-dihydro-1H-1,3-benzodiazol-2-one
Saber, Asmaa
Sebbar, Nada Kheira
Hokelek, Tuncer
El Hafi, Mohamed
Mague, Joel T.
Essassi, El Mokhtar
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1842 - +
[38] Base-Free Synthesis and Synthetic Applications of Novel 3-(Organochalcogenyl)prop-2-yn-1-yl Esters: Promising Anticancer Agents
Gritzenco, Fabiane
Kazmierczak, Jean C.
Anjos, Thiago
Speranca, Adriane
Peixoto, Maura L. B.
Godoi, Marcelo
Ledebuhr, Kauane N. B.
Bruning, Cesar Augusto
Zamin, Lauren L.
Godoi, Benhur
SYNTHESIS-STUTTGART, 2021, 53 (15): : 2676 - 2688
[39] Thermal and Crystallographic Studies of 1-(2-Fluoro-4-Nitrophenyl)-4-(Prop-2-yn-1-yl)Piperazine Single Crystal
Satish Kumar Awasthi
Chiranjeev Sharma
Monika Yadav
Gunjan Pandey
Proceedings of the National Academy of Sciences, India Section A: Physical Sciences, 2014, 84 : 19 - 25
[40] Cyclization of trifluoro-N-(prop-2-yn-1-yl)methanesulfonamides to N-(hydroxymethyl)-1,2,3-triazoles
B. A. Shainyan
V. I. Meshcheryakov
I. V. Sterkhova
Russian Journal of Organic Chemistry, 2016, 52 : 1032 - 1035

← 1 2 3 4 5 →