Synthesis of [3-(Trimethylsilyl)prop-2-yn-1-yl] Selenides

被引：4
|
作者：
Musalov, M. V. [1 ]
Andreev, M. V. [1 ]
Amosova, S. V. [1 ]
Larina, L. I. [1 ]
Potapov, V. A. [1 ]
机构：
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Ul Favorskogo 1, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 53卷 / 10期
关键词：
PROPARGYL SELENIDES; TELLURIDES; ANIONS;
D O I：
10.1134/S1070428017100049
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Efficient and selective methods have been developed for the synthesis of previously unknown organyl [3-(trimethylsilyl)prop-2-yn-1-yl] selenides, organyl prop-2-yn-1-yl selenides, and bis[3-(trimethyl-silyl)prop-2-yn-1-yl] selenide by reactions of 3-bromo-1-(trimethylsilyl)prop-1-yne with the corresponding organylselenolates and sodium selenide generated from diorganyl diselenides or elemental selenium by the action of sodium tetrahydridoborate.
引用
收藏
页码：1510 / 1513
页数：4
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