Electricity mediated [3+2]-cycloaddition of N-sulfonylcyclopropanes with olefins via N-centered radical intermediates: access to cyclopentane analogs

被引：13
|
作者：
Saha, Debarshi [1 ]
Taily, Irshad Maajid [1 ]
Banerjee, Nakshatra [1 ]
Banerjee, Prabal [1 ]
机构：
[1] Indian Inst Technol IIT, Dept Chem, Lab 406, Rupnagar 140001, Punjab, India
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 36期
关键词：
3+2 ANNULATION; CYCLOPROPYLANILINES; DERIVATIVES; GENERATION;
D O I：
10.1039/d2cc00761d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An external oxidant free electrochemical strategy is designed towards the beta-scission of strained C-C bonds in cyclopropylamine. Moreover, the mechanistic studies ascertained that the methodology encompasses the N-center radical (NCRs) route and provides access to di- or tri-substituted cyclopentane analogs.
引用
收藏
页码：5459 / 5462
页数：5
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