Electricity mediated [3+2]-cycloaddition of N-sulfonylcyclopropanes with olefins via N-centered radical intermediates: access to cyclopentane analogs

被引：13

作者：

Saha, Debarshi ^{[1
]}

Taily, Irshad Maajid ^{[1
]}

Banerjee, Nakshatra ^{[1
]}

Banerjee, Prabal ^{[1
]}

机构：

[1] Indian Inst Technol IIT, Dept Chem, Lab 406, Rupnagar 140001, Punjab, India

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 36期

关键词：

3+2 ANNULATION; CYCLOPROPYLANILINES; DERIVATIVES; GENERATION;

D O I：

10.1039/d2cc00761d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An external oxidant free electrochemical strategy is designed towards the beta-scission of strained C-C bonds in cyclopropylamine. Moreover, the mechanistic studies ascertained that the methodology encompasses the N-center radical (NCRs) route and provides access to di- or tri-substituted cyclopentane analogs.

引用

页码：5459 / 5462

页数：5

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