An investigation into the electro-oxidation of ethanol and 2-propanol for application in direct alcohol fuel cells (DAFCs)

被引：61
|
作者：
Sen Gupta, S [1 ]
Datta, J [1 ]
机构：
[1] Bengal Engn & Sci Univ, Dept Chem, Sibpur 711103, Howrah, India
来源：
JOURNAL OF CHEMICAL SCIENCES | 2005年 / 117卷 / 04期
关键词：
platinized carbon electrode; ethanol; 2-propanol; electro-oxidation; charge transfer resistance;
D O I：
10.1007/BF02708448
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A comparative study of the electro-oxidation of ethanol and 2-propanol was carried out on carbon-supported platinum particles. Cyclic voltammetry, steady state polarisation, and electrochemical impedance spectroscopy were used to investigate the oxidation reactions. A difference in the mechanistic behaviour of the oxidation of ethanol and 2-propanol on Pt was observed, thereby highlighting the fact that the molecular structure of the alcohol has great influence on its electroreactivity. The study emphasizes the fact that 2-propanol is a promising fuel candidate for a direct alcohol fuel cell.
引用
下载
收藏
页码：337 / 344
页数：8
相关论文
共 50 条
  • [41] IrOx-Pt electrode for the electro-oxidation of ethanol in alkaline-type direct ethanol fuel cells: an excellent CO-tolerant catalyst
    Islam, Md. Fahamidul
    Ahmed, Jahir
    Faisal, M.
    Algethami, Jari S.
    Aoki, Kentaro
    Nagao, Yuki
    Harraz, Farid A.
    Hasnat, Mohammad A.
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (41) : 18933 - 18944
  • [42] Comparative investigation of the cardiovascular effects of methanol, ethanol, 1-propanol and 2-propanol
    Maehler, R
    Kameda, G
    Dadmarz, M
    Vogel, WH
    NAUNYN-SCHMIEDEBERGS ARCHIVES OF PHARMACOLOGY, 1998, 358 (04) : R785 - R785
  • [43] Effect of addition of rhenium to Pt-based anode catalysts in electro-oxidation of ethanol in direct ethanol PEM fuel cell
    Tayal, Jyoti
    Rawat, Bhuvnesh
    Basu, Suddhasatwa
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (05) : 4597 - 4605
  • [44] Investigation of electrocatalytic activity of NiTPPBr6 on the graphite electrode for oxidation of methanol, ethanol, 1-propanol and 2-propanol
    Bahrami, Arezo
    Jafarian, Majid
    Ferdowsi, Ghodsiyeh Sadat
    Rayati, Saeed
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2021, 25 (03) : 247 - 253
  • [45] Enhancement of glucose electro-oxidation by an external electromagnetic field in direct-mode fuel cells
    Spets, J. -P.
    Kuosa, M. A.
    Kiros, Y.
    Anttila, T.
    Rantanen, J.
    Lampinen, M. J.
    Saari, K.
    JOURNAL OF POWER SOURCES, 2010, 195 (02) : 475 - 479
  • [46] Promoting Effect of Cu on Pd Applied to the Hydrazine Electro-Oxidation and Direct Hydrazine Fuel Cells
    Crisafulli, Rudy
    de Paula, Dryade Ferreira
    Zignani, Sabrina C.
    Spadaro, Lorenzo
    Palella, Alessandra
    Boninelli, Simona
    Dias, Jose A.
    Linares, Jose J.
    CATALYSTS, 2022, 12 (12)
  • [47] Direct electro-oxidation of acetic acid in a solid oxide fuel cell
    Kaklidis, N.
    Pekridis, G.
    Besikiotis, V.
    Athanasiou, C.
    Marnellos, G. E.
    SOLID STATE IONICS, 2012, 225 : 398 - 407
  • [48] Chemometric Investigation of Platinum Electrodeposition on Titanium Substrates for Ethanol Electro-oxidation
    Santos, Joao Paulo Tenorio da Silva
    Lemos, Sherlan Guimaraes
    Gromboni, Murilo Fernando
    Del Colle, Vinicius
    Mascarenhas, Artur Jose Santos
    Fernandes, Valeria Cristina
    ELECTROCATALYSIS, 2023, 14 (04) : 570 - 580
  • [49] Chemometric Investigation of Platinum Electrodeposition on Titanium Substrates for Ethanol Electro-oxidation
    João Paulo Tenório da Silva Santos
    Sherlan Guimarães Lemos
    Murilo Fernando Gromboni
    Vinicius Del Colle
    Artur José Santos Mascarenhas
    Valéria Cristina Fernandes
    Electrocatalysis, 2023, 14 : 570 - 580
  • [50] PHOTOCHEMICAL CO-OXIDATION OF BENZALDEHYDE WITH 2-PROPANOL AND WITH BENZYL ALCOHOL
    BACKSTRO.HL
    AQUIST, CF
    ACTA CHEMICA SCANDINAVICA, 1970, 24 (04): : 1431 - &
12345