Promoting Effect of Cu on Pd Applied to the Hydrazine Electro-Oxidation and Direct Hydrazine Fuel Cells

Use of liquid fuels in fuel cells is advantageous due to the easier and safer handling, transportation, and storage. Among the different options, hydrazine is of interest since the formation of highly poisoning carbonaceous species is avoided, in addition to its high energy density. In the search for more active direct hydrazine fuel cells (DHFC), this study analyzes the influence of Cu as an auxiliary metal on Pd. Three different PdxCu/C (x = 3, 1, and 0.33) catalysts were prepared by chemical reduction with NaBH4. The materials were physiochemically characterized by X-ray diffraction, energy-dispersive X-ray spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. Electrochemical analysis in a three-electrode glass cell and a single-cell DHFC was also carried out to study the impact on the electroactivity. Cu exerts a beneficial effect by reducing the adsorption energies of the adsorbed species and donating oxidized species for the completion of the hydrazine electro-oxidation, optimally balanced in the Pd1Cu/C (maximum power density of 180 mW cm(-2)). As a counterpoint, Cu slightly promotes the non-faradaic decomposition of hydrazine, seen by a larger H-2 signal in mass spectroscopy in the anode exhaust at high current densities, which results in a slight loss in faradaic efficiency.