Bonding situation in Be[N(SiMe3)2]2 - an experimental and computational study

被引：34
|
作者：
Naglav, D. [1 ]
Neumann, A. [1 ]
Blaeser, D. [1 ]
Woelper, C. [1 ]
Haack, R. [1 ]
Jansen, G. [1 ]
Schulz, S. [1 ]
机构：
[1] Univ Duisburg Essen, D-45117 Essen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 18期
关键词：
SOLID-STATE STRUCTURES; STRUCTURAL-CHARACTERIZATION; ELECTRON-DENSITY; COVALENT RADII; BASIS-SETS; BERYLLIUM; APPROXIMATION; TOXICITY; ENERGY;
D O I：
10.1039/c4cc09732g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The solid state structure of Be[N(SiMe3)(2)](2) (1) was determined by in situ crystallisation and the bonding situation investigated by quantum chemical calculations. The Be-N bond is predominantly ionic, but some evidence for the presence of a partial Be-N double bond character was found.
引用
收藏
页码：3889 / 3891
页数：3
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