Bonding situation in Be[N(SiMe3)2]2 - an experimental and computational study

被引：34

作者：

Naglav, D. ^{[1
]}

Neumann, A. ^{[1
]}

Blaeser, D. ^{[1
]}

Woelper, C. ^{[1
]}

Haack, R. ^{[1
]}

Jansen, G. ^{[1
]}

Schulz, S. ^{[1
]}

机构：

[1] Univ Duisburg Essen, D-45117 Essen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 18期

关键词：

SOLID-STATE STRUCTURES; STRUCTURAL-CHARACTERIZATION; ELECTRON-DENSITY; COVALENT RADII; BASIS-SETS; BERYLLIUM; APPROXIMATION; TOXICITY; ENERGY;

D O I：

10.1039/c4cc09732g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solid state structure of Be[N(SiMe3)(2)](2) (1) was determined by in situ crystallisation and the bonding situation investigated by quantum chemical calculations. The Be-N bond is predominantly ionic, but some evidence for the presence of a partial Be-N double bond character was found.

引用

页码：3889 / 3891

页数：3

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