[3+2] Cycloaddition of Nitrile Ylides with Diazonium Salts: Copper-Catalyzed One-Pot Synthesis of Fully Substituted 1,2,4-Triazoles

被引：35

作者：

Li, Huihuang ^{[1
]}

Wu, Xueli ^{[1
]}

Hao, Weiwei ^{[1
]}

Li, Haiyan ^{[1
]}

Zhao, Yanwei ^{[1
]}

Wang, Yaxiong ^{[1
]}

Lian, Pengcheng ^{[1
]}

Zheng, Yonggao ^{[1
]}

Bao, Xiaoguang ^{[1
]}

Wan, Xiaobing ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 17期

关键词：

SOLID-PHASE SYNTHESIS; ARYLDIAZONIUM SALTS; COORDINATION CHEMISTRY; CARBENE COMPLEXES; ORGANIC-SYNTHESIS; DERIVATIVES; EFFICIENT; ROUTE; LIGHT; OXADIAZOLES;

D O I：

10.1021/acs.orglett.8b02172

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel [3 + 2] cycloaddition between nitrile ylides and diazonium salts was well-established. This copper-catalyzed three-component reaction was distinguished by mild conditions, ready availability, and operational simplicity, thus opening access to 1,2,4-triazoles with a diverse set of substitution patterns.

引用

页码：5224 / 5227

页数：4

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