Novel synthesis of 2-arylbenzothiazoles

被引:15
|
作者
Shirinian, VZ [1 ]
Melkova, SY [1 ]
Belen'kii, LI [1 ]
Krayushkin, MM [1 ]
机构
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia
基金
美国国家航空航天局; 美国国家科学基金会;
关键词
2-arylbenzothiazoles; synthesis; o-aminothiophenol; reactions with dibenzyl; disulfides; benzyl mercaptan; and sodium benzyl thiosulfate;
D O I
10.1007/BF02494924
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new method for the synthesis of 2-arylbenzothiazoles by the reaction of dibenzyl disulfides with o-aminothiophenol is suggested. A possible mechanism of the new transformation is discussed. 2-Phenylbenzothiazole call also be prepared by reactions of o-aminothiophenol with benzyl mercaptane or sodium benzyl thiosulfate.
引用
收藏
页码:1859 / 1862
页数:4
相关论文
共 50 条
  • [21] Novel Green Procedure for the Synthesis of 2-Arylbenzothiazoles Under Microwave Irradiation in Peg 200 Or Peg 400
    Deligeorgiev, Todor G.
    Kaloyanova, Stefka
    Vasilev, Aleksey
    Vaquero, Juan J.
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (11) : 2292 - 2302
  • [22] Electrooxidative cyclization of benzylideneaminothiophenols to the corresponding 2-arylbenzothiazoles
    Okimoto, Mitsuhiro
    Yoshida, Takashi
    Hoshi, Masayuki
    Hattori, Kazuyuki
    Komata, Masashi
    Tomozawa, Kenta
    Chiba, Tomohito
    [J]. HETEROCYCLES, 2008, 75 (01) : 35 - 42
  • [23] A Heterogeneous catalyst for efficient and green synthesis of 2-arylbenzothiazoles and 2-arylbenzimidazoles
    Fazaeli, Razieh
    Aliyan, Hamid
    [J]. APPLIED CATALYSIS A-GENERAL, 2009, 353 (01) : 74 - 79
  • [24] Metal-Free Synthesis of 2-Arylbenzothiazoles from Aldehydes, Amines, and Thiocyanate
    Dey, Amrita
    Hajra, Alakananda
    [J]. ORGANIC LETTERS, 2019, 21 (06) : 1686 - 1689
  • [25] Novel, Mild, and Highly Efficient Method for the Synthesis of 2-Arylbenzothiazoles by the Oxidation of 2-Arylbenzothiazolines with Silicon Lewis Acids
    Sonika
    Meenakshi
    Malhotra, Rajesh
    [J]. SYNTHETIC COMMUNICATIONS, 2011, 41 (01) : 136 - 146
  • [26] Caffeine hydrogen sulfate: a recyclable solid acid catalyst for mechanochemical synthesis of 2-arylbenzothiazoles
    Kalal, Priyanka
    Sethiya, Ayushi
    Soni, Jay
    Patel, Isha
    Gandhi, Divyani
    Agarwal, Shikha
    [J]. JOURNAL OF SULFUR CHEMISTRY, 2022, 43 (03) : 233 - 241
  • [27] Synthesis of 2-arylbenzothiazoles by the reaction ofo-aminothiophenol with bis(arylmethyl)disulfides
    V. Z. Shirinyan
    S. Yu. Melkova
    L. I. Belen'kii
    M. M. Krayushkin
    [J]. Chemistry of Heterocyclic Compounds, 2000, 36 (2) : 228 - 228
  • [28] Synthesis of carbon-11 labeled fluorinated 2-arylbenzothiazoles as novel potential PET cancer imaging agents
    Wang, Min
    Gao, Mingzhang
    Mock, Bruce H.
    Miller, Kathy D.
    Sledge, George W.
    Hutchins, Gary D.
    Zheng, Qi-Huang
    [J]. BIOORGANIC & MEDICINAL CHEMISTRY, 2006, 14 (24) : 8599 - 8607
  • [29] Catalyst-Free Synthesis of 2-Arylbenzothiazoles in an Air/DMSO Oxidant System
    Hu, Renhe
    Li, Xiaotong
    Tong, Yao
    Miao, Dazhuang
    Pan, Qiang
    Jiang, Zengqiang
    Gan, Haifeng
    Han, Shiqing
    [J]. SYNLETT, 2016, 27 (09) : 1387 - 1390
  • [30] Synthesis of 2-arylbenzothiazoles by interaction of o-aminothiophenol with bis(arylmethyl) disulfides
    Shirinyan, VZ
    Melkova, SY
    Belenkii, LI
    Krayushkin, MM
    [J]. KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2000, (02): : 268 - 268