A Heterogeneous catalyst for efficient and green synthesis of 2-arylbenzothiazoles and 2-arylbenzimidazoles

被引:71
|
作者
Fazaeli, Razieh [1 ]
Aliyan, Hamid [1 ]
机构
[1] Islamic Azad Univ, Dept Chem, Shahreza Branch, Shahreza Esfahan 86145311, Iran
关键词
Heteropoly acids (HPAs); Polyoxometalates (POMs); 2-Arylbenzimidazoles; 2-Arylbenzothiazoles; o-Aminothiophenols; o-Phenylenediamine (OPD); Heterogeneous; Supported catalyst; ONE-POT SYNTHESIS; SOLVENT-FREE; 1,5-BENZODIAZEPINE DERIVATIVES; BIOLOGICAL-ACTIVITY; HETEROPOLY ACIDS; SILICA-GEL; FACILE; BENZIMIDAZOLES; BENZOXAZOLES; DESIGN;
D O I
10.1016/j.apcata.2008.10.035
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Solid heteropoly acid supported on silica gel (Cu3/2PMo12O40/SiO2) is easily used as a heterogonous, reusable and efficient catalyst for synthesis of 2-arylbenzimidazoles and 2-arylbenzothiazoles by reaction of o-phenylenediamine and o-aminothiophenol with different aldehydes under various conditions (in solvent, under solvent-free conditions, microwave and ultrasonic wave irradiation). The catalyst can be reused for several times but it will be less active. (C) 2008 Elsevier B.V. All rights reserved.
引用
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页码:74 / 79
页数:6
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