Method for the preparation of aluminum hydride

被引：9

作者：

Bakum, S. I. ^{[1
]}

Kuznetsova, S. F. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 12期

关键词：

Aluminum Chloride; Benzyl Chlo Ride; Aluminum Hydride; Lithium Aluminum Hydride; Chlorosi Lane;

D O I：

10.1134/S0036023610120028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for the preparation of aluminum hydride is proposed by reacting SiCl(4) or SiHCl(3) with lithium aluminum hydride in ether/toluene. The method yields hexagonal crystalline AlH(3) with a low chlorine content, increased thermal stability, and high reproducibility.

引用

页码：1830 / 1832

页数：3

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