A new supramolecular compound based on Mn(II)-Schiff-base and Keggin-type [PMo12O40]3-

被引：1
|
作者：
Wei, M. L. [1 ]
Zhuang, P. F. [1 ]
Sun, R. P. [1 ]
Li, H. H. [1 ]
机构：
[1] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 01期
基金：
中国国家自然科学基金;
关键词：
SCHIFF-BASE; MOLECULES;
D O I：
10.1134/S1070328411010167
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new organometallic-inorganic hybrid compound {[Mn(L)(2)](2)[PMo12O40][NO3] center dot 4CH(3)OH center dot 3H(2)O} (n) (I), where L is 1,4-bis(4-imidazolyl)-2,3-diaza-1,3-butadiene) was synthesized in situ from [PMo12O40](3-), Mn2+ and L reaction in an H2O-DMSO-CH3OH mixture at room temperature, and the product was structurally characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound I is constructed from alternating layers of the metal-Schiff-base cation and Keggin anions based on electrostatic forces and hydrogen bond interactions.
引用
收藏
页码：30 / 35
页数：6
相关论文
共 50 条
  • [41] A new layered compound containing [PMo12O40]3- and both 5- and 6-coordinated homoleptic (1-(2-chloroethyl)tetrazole)copper(II) cations
    Stassen, AF
    Ferrero, EM
    Giménez-Saiz, C
    Coronado, E
    Haasnoot, JG
    Reedijk, J
    MONATSHEFTE FUR CHEMIE, 2003, 134 (02): : 255 - 264
  • [42] KEGGIN COMPLEX WITH DECREASED PSEUDOSYMMETRY IN STRUCTURE OF H3[PMO12O40].(13-14)H2O
    DAMOUR, H
    ALLMANN, R
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1976, 143 : 1 - 13
  • [43] A novel supramolecular organic-inorganic adduct containing α-Keggin-type [PW12O40]3- anions and benzo-15-crown-5 molecules
    Paz, FAA
    Sousa, FL
    Soares-Santos, PCR
    Cavaleiro, AMV
    Nogueira, HIS
    Klinowski, J
    Trindade, T
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : M1 - M5
  • [44] Two new supramolecular assemblies based on Keggin-type polyoxometalates through Ag•••O and π•••π stacking interactions
    Chen, Jing
    Sha, Jing-quan
    Peng, Jun
    Shi, Zhen-yu
    Tian, Ai-xiang
    Zhang, Peng-peng
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 917 (01) : 10 - 14
  • [45] Two new organic-inorganic hybrid compounds induced by -[Mo8O26]4- and[PMo12O40]3-
    Ying, Jun
    Li, Ting-Ting
    Liu, Jia-Ni
    Tian, Yan
    Ni, Huai-Ping
    Ji, Xue-Bin
    Liu, Guo-Cheng
    Tian, Ai-Xiang
    JOURNAL OF COORDINATION CHEMISTRY, 2017, 70 (11) : 1872 - 1881
  • [46] Coordination and supramolecular assemblies of K+/Ln3+ to perhydroxycucurbit[5] uril in the presence of [PMo12O40]3-: potential application in isolation of light lanthanides
    Han, Bao-Xia
    Wang, Chuan-Zeng
    Chen, Kai
    Xiao, Xin
    Tao, Zhu
    Xue, Sai-Feng
    Zhang, Yun-Qian
    Zhu, Qian-Jiang
    CRYSTENGCOMM, 2014, 16 (09): : 1615 - 1619
  • [47] The solid-state thermal rearrangement of the Dawson anion [P2Mo18O62]6- into a Keggin-type [PMo12O40]3--containing phase and their reactivity in the oxidative dehydrogenation of isobutyraldehyde
    Hu, J
    Burns, RC
    Guerbois, JP
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 152 (1-2) : 141 - 155
  • [48] KINETICS OF OXYGEN-ATOM TRANSFER-REACTIONS OF ALPHA-[PMO12O40](3-) AND OF A-BETA-[PMO3W9O40](3-) ANION SALTS WITH PPH(3) IN NONAQUEOUS SOLUTION
    KAWAFUNE, I
    MATSUBAYASHI, G
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (03) : 838 - 842
  • [49] Assembly of Hybrid Materials Based on a LanthanideOrganic Framework and a Keggin-Type [PMo12xVxO40](3+x) (x=1, 2) Cluster
    Liu, Xiaoyu
    Wang, Li
    Yin, Xuena
    Huang, Rudan
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (12) : 2181 - 2187
  • [50] Preparation and voltammetric characterization of Keggin-type tungstovanadate [VW12O40]3- and [V(VW11)O40]4- complexes
    Himeno, S
    Takamoto, M
    Higuchi, A
    Maekawa, M
    INORGANICA CHIMICA ACTA, 2003, 348 : 57 - 62
12345