A new supramolecular compound based on Mn(II)-Schiff-base and Keggin-type [PMo12O40]3-

被引：1
|
作者：
Wei, M. L. [1 ]
Zhuang, P. F. [1 ]
Sun, R. P. [1 ]
Li, H. H. [1 ]
机构：
[1] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 01期
基金：
中国国家自然科学基金;
关键词：
SCHIFF-BASE; MOLECULES;
D O I：
10.1134/S1070328411010167
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new organometallic-inorganic hybrid compound {[Mn(L)(2)](2)[PMo12O40][NO3] center dot 4CH(3)OH center dot 3H(2)O} (n) (I), where L is 1,4-bis(4-imidazolyl)-2,3-diaza-1,3-butadiene) was synthesized in situ from [PMo12O40](3-), Mn2+ and L reaction in an H2O-DMSO-CH3OH mixture at room temperature, and the product was structurally characterized by elemental analysis, infrared spectroscopy, and single-crystal X-ray diffraction analysis. Compound I is constructed from alternating layers of the metal-Schiff-base cation and Keggin anions based on electrostatic forces and hydrogen bond interactions.
引用
收藏
页码：30 / 35
页数：6
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