Solubility Prediction for the System of MgCl2-MgSO4-MgB4O7-H2O at 298.15 K Using the Ion-Interaction Model

被引:6
|
作者
Meng, Lingzong [1 ,2 ]
Deng, Tianlong [2 ]
机构
[1] Linyi Univ, Coll Chem & Environm, Linyi 276005, Peoples R China
[2] Tianjin Univ Sci & Technol, Tianjin Key Lab Marine Resources & Chem, Tianjin 300457, Peoples R China
关键词
THERMODYNAMIC PROPERTIES; NATURAL-WATERS; MINERAL SOLUBILITIES; PHASE-EQUILIBRIUM; 25-DEGREES-C; COEFFICIENTS; LAKE;
D O I
10.1134/S0036023611080158
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Solubilities for the system of MgCl2-MgSO4-MgB4O7-H2O at 298.15 K were calculated by using Pitzer and its extended HW model. The values of the parameters were derived from either literature or through fitting with the solubility data of the relative ternary system in literature. A comparison with the experimental values and calculated solubility data shows that the model can be used successfully to predict the solubilities of the mentioned system. Parameters got in this study can be further used for solubility prediction of more complicated system containing MgB4O7, and the results could provide a theoretical basis for exaction of magnesium borate from salt lake brine resources.
引用
下载
收藏
页码:1335 / 1338
页数:4
相关论文
共 50 条
  • [41] The phase diagrams of the systems MgCl2 + MgB6O10 + H2O and MgSO4 + MgB6O10 + H2O at 323.15 K and Pitzer model
    Meng, Ling-zong
    Deng, Tian-long
    Guo, Ya-fei
    Li, Dan
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 86 (10) : 1526 - 1532
  • [42] Solubilities, Densities, and Refractive Indices of the Quaternary System (KCl + MgCl2 + K2B4O7 + MgB4O7 + H2O)
    Jia-tong Wu
    Le Zhang
    Dong-chan Li
    Ya-fei Guo
    Shi-qiang Wang
    Russian Journal of Physical Chemistry A, 2021, 95 : S217 - S221
  • [43] Solubilities, Densities, and Refractive Indices of the Quaternary System (KCl + MgCl2 + K2B4O7 + MgB4O7 + H2O)
    Wu, Jia-tong
    Zhang, Le
    Li, Dong-chan
    Guo, Ya-fei
    Wang, Shi-qiang
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 95 (SUPPL 2) : S217 - S221
  • [44] The phase diagrams of the systems MgCl2 + MgB6O10 + H2O and MgSO4 + MgB6O10 + H2O at 323.15 K and Pitzer model
    Ling-zong Meng
    Tian-long Deng
    Ya-fei Guo
    Dan Li
    Russian Journal of Physical Chemistry A, 2012, 86 : 1526 - 1532
  • [45] Solubility and Crystallization in the System MgCl2–MgSO4–H2O at 50 and 75°C
    Chr. Balarew
    S. Tepavitcharova
    D. Rabadjieva
    W. Voigt
    Journal of Solution Chemistry, 2001, 30 : 815 - 823
  • [46] Studies on Metastable Phase Equilibria in the Ternary Systems KCl-MgCl2-H2O and MgB4O7-MgCl2-H2O at 273 K
    Xu, Jingshu
    Song, Yanyu
    Gao, Yunyun
    Sang, Shihua
    He, Xiaofeng
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2019, 52 (10) : 783 - 788
  • [47] SOLUBILITY POLYTHERM OF THE HCONH2-MGSO4-H2O SYSTEM
    YUGAI, MR
    TUKHTAEV, S
    IRGASHEV, IK
    BEGLOV, BM
    ZHURNAL NEORGANICHESKOI KHIMII, 1980, 25 (02): : 581 - 583
  • [48] Isopiestic investigation of the osmotic and activity coefficients of aqueous MgSO4 and the solubility of MgSO4•7H2O(cr) at 298.15 K:: Thermodynamic properties of the MgSO4+H2O system to 440 K. (vol 43, pg 791, 1998)
    Archer, DG
    Rard, JA
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (04): : 716 - 716
  • [49] The phase and density diagrams of the systems MgCl2–MgB4O7–H2O and KCl–K2B4O7–H2O at 273 K
    Xiang-Po Zhao
    Xue-Ping Zhang
    Shi-Hua Sang
    Russian Journal of Physical Chemistry A, 2017, 91 : 1932 - 1938
  • [50] Solubility Prediction of System KCl-K2SO4-H2O Using Thermodynamic Model
    尹霞
    汪琼
    吴玉双
    湖南大学学报(自然科学版), 2011, (02) : 65 - 69