Band-gap Tuning and Magnetic Properties of Heterovalent ions (Ba, Sr and Ca) Substituted BiFeO3 Nanoparticles

被引：1
|
作者：
Chauhan, Sunil [1 ]
Kumar, Manoj [1 ]
Katyal, S. C. [1 ]
机构：
[1] Jaypee Inst Informat Technol, Dept Phys & Mat Sci & Engn, Noida 201307, India
来源：
DAE SOLID STATE PHYSICS SYMPOSIUM 2015 | 2016年 / 1731卷
关键词：
Multiferroics; Raman spectroscopy; Optical properties; nanocrystalline magnetic materials;
D O I：
10.1063/1.4948135
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
A Comparative study of heterovalent Ba, Sr and Ca ions substitution on the structural, vibrational, optical and magnetic properties of BiFeO3 nanoparticles was carried out. The distorted rhombohedral structure was confirmed from both X-ray diffraction and Raman spectroscopy techniques in pure BiFeO3 and Bi(0.85)A(0.15)FeO(3) ( A=Ba, Sr and Ca) samples. UV-Visible spectroscopy results show that the band-gap of BiFeO3 nanoparticles can be tuned by heterovalent ions substitution from 2.12 eV for BiFeO3 to 2.10, 2.06 and 2.03 eV for Ca, Sr and Ba substituted BiFeO3 nanoparticles respectively. The magnetic measurements indicate enhancement in magnetization for heterovalent A(2+) substituted BiFeO3 samples and the magnetization increases with increase of ionic radius of the substituted ions.
引用
下载
收藏
页数：3
相关论文
共 50 条
  • [31] Effect of Non-magnetic Ions Substitution on Structural, Magnetic and Optical Properties of BiFeO3 Nanoparticles
    Arora, Manisha
    Chauhan, Sunil
    Sati, P. C.
    Kumar, Manoj
    JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, 2014, 27 (08) : 1867 - 1871
  • [32] Band-Gap Reduction in (BiCrO3)m/(BiFeO3)n Superlattices: Designing Low-Band-Gap Ferroelectrics
    Zhang, S.
    Xiao, H. Y.
    Peng, S. M.
    Yang, G. X.
    Liu, Z. J.
    Zu, X. T.
    Li, S.
    Singh, D. J.
    Martin, L. W.
    Qiao, L.
    PHYSICAL REVIEW APPLIED, 2018, 10 (04):
  • [33] Enhanced photocatalytic activity of Ba doped BiFeO3 by turning morphologies and band gap
    Zhang, Yaowen
    Yang, Yonghang
    Dong, Zhichen
    Shen, Junchen
    Song, Qinxin
    Wang, Xingfu
    Mao, Weiwei
    Pu, Yong
    Li, Xing'ao
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2020, 31 (18) : 15007 - 15012
  • [34] Effect of Non-magnetic Ions Substitution on Structural, Magnetic and Optical Properties of BiFeO3 Nanoparticles
    Manisha Arora
    Sunil Chauhan
    P. C. Sati
    Manoj Kumar
    Journal of Superconductivity and Novel Magnetism, 2014, 27 : 1867 - 1871
  • [35] Enhanced photocatalytic activity of Ba doped BiFeO3 by turning morphologies and band gap
    Yaowen Zhang
    Yonghang Yang
    Zhichen Dong
    Junchen Shen
    Qinxin Song
    Xingfu Wang
    Weiwei Mao
    Yong Pu
    Xing’ao Li
    Journal of Materials Science: Materials in Electronics, 2020, 31 : 15007 - 15012
  • [36] Effect of diamagnetic Ca, Sr, Pb, and Ba substitution on the crystal structure and multiferroic properties of the BiFeO3 perovskite
    Khomchenko, V. A.
    Kiselev, D. A.
    Vieira, J. M.
    Jian, Li
    Kholkin, A. L.
    Lopes, A. M. L.
    Pogorelov, Y. G.
    Araujo, J. P.
    Maglione, M.
    JOURNAL OF APPLIED PHYSICS, 2008, 103 (02)
  • [37] Structural Phase Transformation, Magnetic and Optical Properties of Ho3+ Substituted BiFeO3 Nanoparticles
    Manoj Kumar
    Himanshu Pandey
    Journal of Superconductivity and Novel Magnetism, 2023, 36 : 1269 - 1276
  • [38] Ti doping-induced magnetic and morphological transformations in Sr- and Ca-substituted BiFeO3
    Khomchenko, V. A.
    Paixao, J. A.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2016, 28 (16)
  • [39] Structural Phase Transformation, Magnetic and Optical Properties of Ho3+ Substituted BiFeO3 Nanoparticles
    Kumar, Manoj
    Pandey, Himanshu
    JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, 2023, 36 (04) : 1269 - 1276
  • [40] Unusual magnetic properties of (Sr, Mn)-substituted BiFeO3 near the polar/ antipolar phase boundary
    Khomchenko, V. A.
    Das, M.
    Henriques, M. S. C.
    Paixao, J. A.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2023, 585
12345