Electrical conductivity of Ag2S-Ga2S3-GeS2 glasses

被引:7
|
作者
Chbani, N [1 ]
Ferhat, A [1 ]
Loireau-Lozac'h, AM [1 ]
Dugue, J [1 ]
机构
[1] Univ Paris 05, Fac Sci Pharmaceut & Biol, Lab Chim Phys & Chim Minerale Struct, F-75270 Paris 06, France
关键词
D O I
10.1016/S0022-3093(98)00410-4
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The Ag2S-Ga2S3-GeS2 pseudo ternary system shows a large glass-forming region. Ternary glass formation does not reach the Ga2S3-Ag2S binary system. Electrical properties of the glasses were investigated by measuring complex impedance. For instance, at 298 K, for the xAg(2)S-Ga2S3-(9 - x)GeS2 compositions (x = 1-6) electrical conductivity and activation energy vary roughly between 10(-10) and 10(-5) S cm(-1), and 0.60 and 0.34 eV, respectively. Ionic transference number measurements and electronic transference number estimates indicate that these glasses are essentially ionic conductors. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:251 / 256
页数:6
相关论文
共 50 条
  • [31] Influence of temperature on the photoluminescence efficiency of chalcogenide GeS2-Ga2S3-Er2S3 glasses
    Ivanova, ZG
    Ganesan, R
    Aneva, Z
    Gopal, ESR
    MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 122 (02): : 152 - 155
  • [32] Structural investigation of Ag2S+B2S3+GeS2 glasses using neutron diffraction
    Mei, Q
    Martin, SW
    PHYSICS AND CHEMISTRY OF GLASSES, 2005, 46 (01): : 51 - 57
  • [33] Vitreous region and properties of glasses of the Ga2S3-GeS2-PbF2 system
    Orkina, T. N.
    Blinov, L. N.
    Gutenev, M. S.
    GLASS PHYSICS AND CHEMISTRY, 2017, 43 (04) : 313 - 318
  • [34] NEW CHALCOHALIDE GLASSES FROM THE SYSTEM GES2-GA2S3-MNCL2
    PETROVA, B
    FRUMAR, M
    CERNOSKOVA, E
    CERNY, V
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1993, 161 : 316 - 319
  • [35] Raman spectroscopic analysis of GeS2-Ga2S3-PbI2 chalcohalide glasses
    Guo, Haitao
    Tao, Haizheng
    Zhai, Yanbo
    Mao, Shun
    Zhao, Xiujian
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 67 (05) : 1351 - 1356
  • [36] Raman spectra study on the GeS2-Ga2S3-KCl system glasses
    Tao, HZ
    Zhao, XJ
    Jing, CB
    Tong, W
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25 (01) : 44 - 47
  • [37] GeS2-Ga2S3-AgI Glasses with High Nonlinear Optical Properties
    Iliopoulos, K.
    Hatzikyriakos, G.
    Couris, S.
    Ren, J.
    Wagner, T.
    Frumar, M.
    Kyriazis, F.
    Yannopoulos, S. N.
    2011 13TH INTERNATIONAL CONFERENCE ON TRANSPARENT OPTICAL NETWORKS (ICTON), 2011,
  • [38] Ion conductive chalcohalide glasses in LiI-Ga2S3-GeS2 system
    Kolar, J.
    Wagner, T.
    Zima, V.
    Stehlik, S.
    Frumarova, B.
    Benes, L.
    Vlcek, M.
    Frumar, M.
    Kasap, S. O.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2011, 357 (11-13) : 2223 - 2227
  • [39] Alkali Halide-Doped Ga2S3–GeS2 Glasses
    Bokova, Maria
    Paraskiva, Alla
    Kassem, Mohammad
    Bychkov, Eugene
    Bokova, Maria (Maria.Bokova@univ-littoral.fr), 1600, Wiley-VCH Verlag (257):
  • [40] ELECTRICAL PROPERTIES OF AS2S3-AG GLASSES
    MARUNO, S
    YAMADA, T
    NODA, M
    KONDO, Y
    JAPANESE JOURNAL OF APPLIED PHYSICS, 1972, 11 (01) : 116 - &