Electrical conductivity of Ag2S-Ga2S3-GeS2 glasses

被引：7

作者：

Chbani, N ^{[1
]}

Ferhat, A ^{[1
]}

Loireau-Lozac'h, AM ^{[1
]}

Dugue, J ^{[1
]}

机构：

[1] Univ Paris 05, Fac Sci Pharmaceut & Biol, Lab Chim Phys & Chim Minerale Struct, F-75270 Paris 06, France

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1998年 / 231卷 / 03期

关键词：

D O I：

10.1016/S0022-3093(98)00410-4

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The Ag2S-Ga2S3-GeS2 pseudo ternary system shows a large glass-forming region. Ternary glass formation does not reach the Ga2S3-Ag2S binary system. Electrical properties of the glasses were investigated by measuring complex impedance. For instance, at 298 K, for the xAg(2)S-Ga2S3-(9 - x)GeS2 compositions (x = 1-6) electrical conductivity and activation energy vary roughly between 10(-10) and 10(-5) S cm(-1), and 0.60 and 0.34 eV, respectively. Ionic transference number measurements and electronic transference number estimates indicate that these glasses are essentially ionic conductors. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：251 / 256

页数：6

共 50 条

[21] Electric conductivity of glasses in the Ga2S3-GeS2-MCl system (M = Li, Na, K, Cs, Ag, and Tl)
Tver'yanovich, YS
Aleksandrov, VV
Murin, IV
Nedoshovenko, EG
GLASS PHYSICS AND CHEMISTRY, 1998, 24 (05) : 446 - 451
[22] Glass formation and luminescence of glasses in the Ga2S3-GeS2-Nd2S3 system
Degtyarev, SV
Man'shina, AA
Kurochkin, AV
Zhuzhel'skii, DV
Grigor'ev, YG
Tver'yanovich, YS
GLASS PHYSICS AND CHEMISTRY, 2001, 27 (03) : 209 - 213
[23] Preparation and characterization of glasses in the LiI+Li2S+GeS2+Ga2S3 system
Saienga, J
Kim, Y
Campbell, B
Martin, SW
SOLID STATE IONICS, 2005, 176 (13-14) : 1229 - 1236
[24] Structure and properties of GeS2-Ga2S3-CdI2 chalcohalide glasses
Guo, Haitao
Zhai, Yanbo
Tao, Haizheng
Dong, Guoping
Zhao, Xiujian
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2007, 138 (03): : 235 - 240
[25] Synthesis and properties of GeS2-Ga2S3-PbI2 chalcohalide glasses
Guo, Haitao
Zhai, Yanbo
Tao, Haizheng
Gong, Yueqiu
Zhao, Xiujian
MATERIALS RESEARCH BULLETIN, 2007, 42 (06) : 1111 - 1118
[26] Frequency upconversion of Er3+ in Ga2S3-GeS2-La2S3 glasses
Kadono, K
Takahashi, M
Higuchi, H
Shojiya, M
Ohtsuki, T
Kawamoto, Y
Peyghambarian, N
RARE-EARTH-DOPED DEVICES, 1997, 2996 : 25 - 31
[27] The comparative structure, properties, and ionic conductivity of LiI+Li2S+GeS2 glasses doped with Ga2S3 and La2S3
Saienga, Jason
Martin, Steve W.
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (14) : 1475 - 1486
[28] Study of Optical Properties of GeS2-Ga2S3-AgCl Glasses
Fan Xin-Ye
Xu Tie-Feng
Shen Xiang
Dai Shi-Xun
Nie Qiu-Hua
Wang Xun-Si
Chen Fei-Fei
JOURNAL OF INORGANIC MATERIALS, 2010, 25 (02) : 191 - 195
[29] Alkali Halide-Doped Ga2S3-GeS2 Glasses
Bokova, Maria
Paraskiva, Alla
Kassem, Mohammad
Bychkov, Eugene
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2020, 257 (11):
[30] IONIC-CONDUCTION IN AS-2S-3 - AG-2S, GES-2 - GES - AG-2S AND P-25-5 - AG-25 GLASSES
KAWAMOTO, Y
NISHIDA, M
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1976, 20 (03) : 393 - 404

← 1 2 3 4 5 →