Luminescent gold(III) alkynyl complexes: Synthesis, structural characterization, and luminescence properties

被引：152

作者：

Yam, VWW ^{[1
]}

Wong, KMC ^{[1
]}

Hung, LL ^{[1
]}

Zhu, NY ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Ctr Carbon Rich Mol & Nano Scale Met Based Mat Re, Hong Kong, Hong Kong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 20期

关键词：

D O I：

10.1002/anie.200500253

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Luminous: The AuIII alkynyl complexes [Au(C∧N∧C)(C≡CR)] [HC^N^CH=2,6-diphenylpyridine, R = C6H5 (1), C6H4-Cl-p (2), C 6H4-OCH3-P (3), C6H 4-NH2-p (4); HC∧N∧CH = 2,6-bis(4-tert-butylphenyl) -pyridine, R = C6H5 (5)] were prepared, and the molecular structure of 1 was characterized (see picture). Complexes 1-5 display luminescence in solution and in the solid state both at low and ambient temperature. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3107 / 3110

页数：4

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