Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands

被引：0
|
作者：
Oleksandra Berezhnytska
Irina Savchenko
Nadiya Ivakha
Olena Trunova
Nataliya Rusakova
Sergiy Smola
Oleksandr Rogovtsov
机构：
[1] NASU,V.I.Vernadsky Institute of General and Inorganic Chemistry
[2] National Taras Shevchenko University of Kyiv,A.V. Bogatsky Physico
[3] NASU,Chemical Institute
来源：
Nanoscale Research Letters | 2017年 / 12卷
关键词：
Neodymium(III); Polymer complexes; Spectra; Structure; Luminescence;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed.
引用
收藏
相关论文
共 50 条
  • [1] Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands
    Berezhnytska, Oleksandra
    Savchenko, Irina
    Ivakha, Nadiya
    Trunova, Olena
    Rusakova, Nataliya
    Smola, Sergiy
    Rogovtsov, Oleksandr
    NANOSCALE RESEARCH LETTERS, 2017, 12
  • [2] Synthesis, Characterization and Luminescent Property of New Iridium(III) Complexes Bearing Pyrrylimine Ligands
    Li Wen-Ying
    Mao Li-Sheng
    Lue Long
    He Hong-Wu
    ACTA CHIMICA SINICA, 2008, 66 (19) : 2141 - 2145
  • [3] Synthesis, characterization, photophysics and electrochemical study of luminescent iridium(III) complexes with isocyanoborate ligands
    Chan, Kin-Cheung
    Chu, Wing-Kin
    Yiu, Shek-Man
    Ko, Chi-Chiu
    DALTON TRANSACTIONS, 2015, 44 (34) : 15135 - 15144
  • [4] Synthesis, Characterization and Antimicrobial Activity of Pr(III) and Nd(III) Complexes of Schiff base Ligands
    Beevi, Y. Jubaira
    Raji, L.
    Panicker, C. Yohannan
    ORIENTAL JOURNAL OF CHEMISTRY, 2011, 27 (01) : 355 - 357
  • [5] Luminescent gold(III) alkynyl complexes: Synthesis, structural characterization, and luminescence properties
    Yam, VWW
    Wong, KMC
    Hung, LL
    Zhu, NY
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (20) : 3107 - 3110
  • [6] Synthesis, characterization and luminescent properties of terbium and europium complexes with ligands from DTPA and pAS
    Zhang, Yuan Jing, 1600, Elsevier Sequoia SA, Lausanne, Switzerland (307):
  • [7] Synthesis, characterization and luminescent properties of terbium and europium complexes with ligands from DTPA and pAS
    Zhang, YJ
    Chen, Y
    De Liu, Q
    Wang, XG
    Li, JR
    Liu, H
    JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 307 : 137 - 140
  • [8] Luminescent terbium complexes with polymer ligands
    Vyprachticky, D
    Cimrová, V
    Kukla, S
    Machová, L
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2004, 69 (02) : 309 - 321
  • [9] Synthesis and Investigation of the Luminescent Properties of Complexes of Europium Ions with Pyridyl-Containing Polymer Ligands
    Yakimanskii, A. V.
    Anufrieva, E. V.
    Krakovyak, M. G.
    Anan'eva, T. D.
    Smyslov, R. Yu.
    Nekrasova, T. N.
    Fomina, M. V.
    Gromov, S. P.
    Alfimov, M. V.
    HIGH ENERGY CHEMISTRY, 2008, 42 (07) : 617 - 619
  • [10] Synthesis and investigation of the luminescent properties of complexes of europium ions with pyridyl-containing polymer ligands
    A. V. Yakimanskii
    E. V. Anufrieva
    M. G. Krakovyak
    T. D. Anan’eva
    R. Yu. Smyslov
    T. N. Nekrasova
    M. V. Fomina
    S. P. Gromov
    M. V. Alfimov
    High Energy Chemistry, 2008, 42 : 617 - 619
12345