Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands

被引：0
|
作者：
Oleksandra Berezhnytska
Irina Savchenko
Nadiya Ivakha
Olena Trunova
Nataliya Rusakova
Sergiy Smola
Oleksandr Rogovtsov
机构：
[1] NASU,V.I.Vernadsky Institute of General and Inorganic Chemistry
[2] National Taras Shevchenko University of Kyiv,A.V. Bogatsky Physico
[3] NASU,Chemical Institute
来源：
Nanoscale Research Letters | 2017年 / 12卷
关键词：
Neodymium(III); Polymer complexes; Spectra; Structure; Luminescence;
D O I：
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摘要：
The neodymium(III) complexes with 2-methyl-5-phenylpenten-1-3,5-dione and allyl-3-oxo-butanoate were synthesized. The polycomplexes on their basis and copolymers with styrene and N-vinylcarbazole in ratio 5:95 were obtained by free-radical polymerization. The results of above studies have shown that the configuration of the chelate unit is unchanged during the polymerization. As a result, the type of coordination was determined and the structure of coordination polyhedra was assumed. The luminescence spectra of obtained metallocomplexes and polymers in solutions and solid state are investigated and analyzed.
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