oxidative coupling;
2-naphthols;
iron pillared clay;
binaphthols;
recycling;
D O I:
10.1023/A:1019001504767
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Iron pillared clays (Fe-PILC) were compared to Fe-exchanged K10 (Fe-K10) for the oxidative coupling of 2-naphthols to the corresponding binaphthols. Fe-K10 appeared as the most efficient heterogeneous catalyst giving nearly quantitative yields with many naphthols. The highest activity displayed by Fe-K10 is attributed to the easier accessibility of catalytic sites of the clay. The catalyst can be recycled several times with success.
机构:
Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R ChinaChinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
Luo, ZB
Liu, QZ
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机构:
Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R ChinaChinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
Liu, QZ
Gong, LZ
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机构:
Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R ChinaChinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
Gong, LZ
Cui, X
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机构:
Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R ChinaChinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
Cui, X
Mi, AQ
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机构:
Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R ChinaChinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China
Mi, AQ
Jiang, YZ
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机构:
Chinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R ChinaChinese Acad Sci, Chengdu Inst Organ Chem, Union Lab Asymmetr Synth, Chengdu 610041, Peoples R China