Oxidative coupling of 2-naphthols catalysed by clays-supported iron catalysts

被引:0
|
作者
Kantam, ML [1 ]
Kavita, B
Figueras, F
机构
[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
[2] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France
关键词
oxidative coupling; 2-naphthols; iron pillared clay; binaphthols; recycling;
D O I
10.1023/A:1019001504767
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Iron pillared clays (Fe-PILC) were compared to Fe-exchanged K10 (Fe-K10) for the oxidative coupling of 2-naphthols to the corresponding binaphthols. Fe-K10 appeared as the most efficient heterogeneous catalyst giving nearly quantitative yields with many naphthols. The highest activity displayed by Fe-K10 is attributed to the easier accessibility of catalytic sites of the clay. The catalyst can be recycled several times with success.
引用
收藏
页码:113 / 115
页数:3
相关论文
共 50 条
  • [21] Chiral α-Aminophosphonates as Ligands in Copper-Catalyzed Asymmetric Oxidative Coupling of 2-Naphthols
    Zuo, Qian-Ming
    Wu, Ming-Ying
    Han, Li-Biao
    Yang, Shang-Dong
    ORGANIC LETTERS, 2024, 26 (25) : 5274 - 5279
  • [22] THE OXIDATIVE CROSS-COUPLING OF SUBSTITUTED 2-NAPHTHOLS .1. THE SCOPE AND LIMITATIONS
    HOVORKA, M
    SCIGEL, R
    GUNTEROVA, J
    TICHY, M
    ZAVADA, J
    TETRAHEDRON, 1992, 48 (43) : 9503 - 9516
  • [23] Dual activation in oxidative coupling of 2-naphthols catalyzed by chiral dinuclear vanadium complexes
    Takizawa, Shinobu
    Katayama, Tomomi
    Somei, Hidenori
    Asano, Yasuaki
    Yoshida, Tomokazu
    Kameyama, Chiaki
    Rajesh, Doss
    Onitsuka, Kiyotaka
    Suzuki, Takeyuki
    Mikami, Masafumi
    Yamatakat, Hiroshi
    Jayaprakash, Doss
    Sasai, Hiroaki
    TETRAHEDRON, 2008, 64 (15) : 3361 - 3371
  • [24] THE OXIDATIVE CROSS-COUPLING OF SUBSTITUTED 2-NAPHTHOLS .2. SELECTIVITY AS A MECHANISTIC PROBE
    HOVORKA, M
    ZAVADA, J
    TETRAHEDRON, 1992, 48 (43) : 9517 - 9530
  • [25] Heterogeneously catalyzed aerobic oxidative biaryl coupling of 2-naphthols and substituted phenols in water
    Matsushita, M
    Kamata, K
    Yamaguchi, K
    Mizuno, N
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (18) : 6632 - 6640
  • [26] Iron Phosphate Catalyzed Asymmetric Cross-Dehydrogenative Coupling of 2-Naphthols with β-Ketoesters
    Narute, Sachin
    Pappo, Doron
    ORGANIC LETTERS, 2017, 19 (11) : 2917 - 2920
  • [28] Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols
    Tkachenko, Nikolay V.
    Bryliakov, Konstantin P.
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2019, 16 (04) : 392 - 398
  • [29] The rational design of novel chiral oxovanadium(IV) complexes for highly enantioselective oxidative coupling of 2-naphthols
    Luo, ZB
    Liu, QZ
    Gong, LZ
    Cui, X
    Mi, A
    Jiang, YZ
    CHEMICAL COMMUNICATIONS, 2002, (08) : 914 - 915
  • [30] Accurate Understanding the Catalytic Role of MnO2in the Oxidative-Coupling of 2-naphthols into 1,1′-bi-2-naphthols
    Wu, Yuting
    Yang, Long
    Wu, Bo
    Li, Jie
    Liu, Binyao
    Ke, Gaili
    Dong, Faqin
    Zhou, Yong
    He, Huichao
    CATALYSIS LETTERS, 2021, 151 (03) : 901 - 908