Bis(2,2′-bipyridine)(pyridin-2-olato)ruthenium(II) hexafluoridophosphate benzene hemisolvate

被引：3
|
作者：
Hamaguchi, Tomohiko [1 ]
Ando, Isao [1 ]
机构：
[1] Fukuoka Univ, Dept Chem, Fac Sci, Jonan Ku, Fukuoka 8140180, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
data-to-parameter ratio = 18.3; Hatom completeness 87%; mean σ(C-C) = 0.010 Å; R factor = 0.047; single-crystal X-ray study; T = 200 K; wR factor = 0.155;
D O I：
10.1107/S1600536811045454
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ru(C5H4NO)(C10H8N2)(2)]PF6 center dot 0.5C(6)H(6), the Ru2+ cation has a distorted octahedral RuN5O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiolate ligand [Santra et al. (1997). J. Chem. Soc. Dalton Trans. pp. 1387-1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent molecule is situated on a twofold rotation axis.
引用
收藏
页码：M1687 / U1632
页数：12
相关论文
共 50 条
  • [31] Photophysical and photoelectrochemical properties of the bis(2,2′-bipyridine)(4,4′-dimethylthio-2,2′-bipyridine)ruthenium(II) complex
    Toma, HE
    Serrasqueiro, RM
    Rocha, RC
    Demets, GJF
    Winnischofer, H
    Araki, K
    Ribeiro, PEA
    Donnici, CL
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 135 (2-3) : 185 - 191
  • [32] INOR 604-Oxidative transformations of bis(2,2'-bipyridine)(1-methyl-1-pyridin-2-yl-ethylamine)ruthenium(II)
    Blauch, David
    Neill, Justin
    Nam, Anna
    Barley, Kevin M.
    Meza, Benjamin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
  • [33] Bis(μ-biphenyl-2,2′-dicarboxylato)bis[(2,2′-bipyridine)copper(II)]
    An, Zhe
    Cui, Rui-Hai
    Zhou, Ru-Jin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M412 - U631
  • [34] Bis(μ-biphenyl-2,2′-dicarboxylato)bis[(2,2′-bipyridine)cobalt(II)]
    An, Zhe
    Niu, Xian-Chun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1556 - U710
  • [35] Bis(μ-biphenyl-2,2′-dicarboxylato)-bis[(2,2′-bipyridine)copper(II)]
    Guo, Hong-Xu
    Liang, Min
    Lin, Bin
    Wang, Qing-Hua
    Li, Xi-Zhong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1171 - U632
  • [36] Bis(2,2′-bipyridine)nitratocopper(II) nitrate
    Marjani, K
    Davies, SC
    Durrant, MC
    Hughes, DL
    Khodamorada, N
    Samodi, A
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M11 - M14
  • [37] BIS(2,2'-BIPYRIDINE)ISOCYANATOCOPPER(II) PERCHLORATE
    MCAULIFFE, CA
    PRITCHARD, RG
    BERMEJO, MR
    GARCIAVAZQUEZ, A
    MACIAS, A
    SANMARTIN, J
    ROMERO, J
    SOUSA, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1316 - 1317
  • [38] SPECTROSCOPIC STUDIES OF BIS COMPLEXES OF RUTHENIUM(II) WITH BENZO SUBSTITUTED ANALOGS OF 2,2'-BIPYRIDINE
    KLASSEN, D
    HEADSTREAM, T
    NEEDELS, D
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1977, 173 (MAR20): : 112 - 112
  • [39] Ruthenium(II) Bis(2,2′-Bipyridine) Interactions with Nucleaobases-Models for DNA Binding
    Larsen, Randy W.
    Whittington, Chrsiti L.
    Kemp, Michael T.
    Word, Tarah
    Woodcock, H. Lee
    Larsen, Randy W.
    BIOPHYSICAL JOURNAL, 2015, 108 (02) : 149A - 150A
  • [40] Acid-Base Properties of the Ground and Excited States of Ruthenium(II) Bis(2,2'-bipyridine) 3-Carboxyl-2,2'-bipyridine
    Zheng, G. Y.
    Wang, Y.
    Rillema, D. P.
    Inorganic Chemistry, 35 (24):
12345